618096-09-6Relevant articles and documents
Catalytic diastereoselective reduction of α,β-epoxy and α,β-aziridinyl ynones
Druais, Valerie,Meyer, Christophe,Cossy, Janine
supporting information; experimental part, p. 516 - 519 (2012/03/26)
The Noyori transfer hydrogenation of α,β-epoxy and α,β-aziridinyl ynones leads to the corresponding α,β-epoxy or α,β-aziridinyl propargylic alcohols with high reagent-controlled diastereoselectivity.
Total synthesis of scytophycin C. 1. Stereoselective syntheses of the C(1)-C(18) segment and the C(19)-C(31) segment
Nakamura, Ryoichi,Tanino, Keiji,Miyashita, Masaaki
, p. 3579 - 3582 (2007/10/03)
[Equation presented] Stereoselective total synthesis of scytophycin C, a marine 22-membered macrolide displaying potent activity against a variety of human carcinoma cell lines, has been reported in which the polypropionate structure bearing contiguous as
Synthesis of the C(19)-C(32) fragment of Scytophycin C via stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminum
Grieco, Paul A.,Speake, Jason D.,Yeo, Sin Koo,Miyashita, Masaaki
, p. 1125 - 1128 (2007/10/03)
The synthesis of the C(19) - C(32) fragment of Scytophycin C is described which features an iterative, stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum and the use of Roush's (S,S)-diisopropyltartrate-E-crotylboronate.
Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins
Miyashita, Masaaki,Yoshihara, Kousei,Kawamine, Katsumi,Hoshino, Masahide,Irie, Hiroshi
, p. 6285 - 6288 (2007/10/02)
A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed