15560-11-9

Basic information

• Product Name: Ethanone, 1-[4-[(2-methylpropyl)thio]phenyl]-
• Synonyms: 1-(4-Isobutylmercapto-phenyl)-aethanon;Ethanone,1-[4-[(2-methylpropyl)thio]phenyl];1-(4-isobutylsulfanyl-phenyl)-ethanone;isobutyl p-acetylphenyl sulfide
• CAS NO: 15560-11-9
• Molecular Formula: C12H16OS
• Molecular Weight: 208.32000
• Mol File: 15560-11-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-[(2-methylpropyl)thio]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-[(2-methylpropyl)thio]phenyl]-(15560-11-9)
• EPA Substance Registry System: Ethanone, 1-[4-[(2-methylpropyl)thio]phenyl]-(15560-11-9)

Safety Data

• Hazardous Substances Data: 15560-11-9(Hazardous Substances Data)

Upstream product

• 13307-61-4 Isobutylthiobenzene 
• 108-24-7 acetic anhydride 
• 99-90-1 para-bromoacetophenone 
• 1518-72-5 diisobutyl disulfide 
• 75-36-5 acetyl chloride 

Downstream Products

• 15560-18-6 (4-Isobutylsulfanyl-phenyl)-acetic acid ethyl ester 
• 15561-03-2 N-Hydroxy-2-(4-isobutylsulfanyl-phenyl)-acetamide 

Relevant articles and documents

Alkyl- and arylthiolation of aryl halides catalyzed by fluorinated bis-imino-nickel NNN pincer complexes [NiCl2{C5H 3N-2,6-(CHNArf)2}]

The synthesis of bis-imino nickel(II) NNN pincer complexes of the type [NiCl2{C5H3N-2,6-(CHNArf) 2}]; Arf= C6H3-2,3-F2 (1), C6H3-2,5-F2 (2), C6H 3-3,4-F2 (3), C6H3-3,5-F2 (4), C6H2-2,3,4-F3 (5), C6H 2-2,3,6-F3 (6), C6H2-2,4,5-F 3 (7), C6H2-2,4,6-F3 (8), has been achieved and their reactivity in alkyl- and arylthiolation reactions of halobenzenes examined. The use of fluorinated substituents Arf on the imines has allowed the tuning of the electronics in these complexes and the influence of these substituents and those of the disulfides in the thiolation reactions have been analyzed.