156280-08-9

Upstream product

• 145397-27-9 [Bis(dicyclohexylamino)phosphanyl](trimethylsilyl)diazomethane 

Downstream Products

• 167955-65-9 3-phenyl-2,2-(bis(dicyclohexylamino)phosphino)(trimethylsilyl)-2H-aziridine 
• 22571-48-8 (diethyl)(dicyclohexylamino)borane 
• 156250-77-0 ((C₆H₁₁)2N)2P(CH₃)C(Si(CH₃)3)Al(CH₃)2 
• 258355-61-2 [CP₃(Si(CH₃)3)(N(C₆H₁₁)2)2(Mo(CO)2(C₅H₅))2] 
• 156250-81-6 C₂₈H₅₃Cl₃GaN₂PSi 
• 156250-80-5 ((C₆H₁₁)2N)2PC(Si(CH₃)3)AlCl₃ 
• 156250-79-2 ((C₆H₁₁)2N)2P(CH₃)C(Si(CH₃)3)In(CH₃)2 
• 156250-82-7 ((C₆H₁₁)2N)2PC(Si(CH₃)3)InCl₃ 
• 156250-78-1 ((C₆H₁₁)2N)2P(CH₃)C(Si(CH₃)3)Ga(CH₃)2 
• 200071-09-6 C₃₇H₆₁N₄PSSi 
• 200071-04-1 2-[Bis(dicyclohexylamino)thioxophosphoranyl]-3-phenyl-2-trimethylsilyl-2H-azirine 
• 200071-22-3 C₃₅H₅₈N₃PSSi 

Relevant academic research and scientific papers

Stereoselectivity and stereospecificity of cyclopropanation reactions with stable (phosphanyl)(silyl)carbenes

The stable (phosphanyl)(silyl)carbenes 1a,b react efficiently with various electron-poor alkenes [methyl acrylate, 3,3,4,4,5,5,6,6,6- nonafluorohex-1-ene, styrene, (Z)- and (E)-2-deuteriostyrene, (E)-t- BuOC(O)CH=CHC(O)OEt, and (E)-Me2NCOCH=CHC

Synthesis and Evolution of Phosphanylcarbene-Borane Adducts

Photolysis of (trimethylsilyl)diazomethane leads to the corresponding stable carbene 1b, which reacts with triethylborane affording a borane-carbene adduct 2b, characterized by spectroscopy in solution before rearrangemen