15648-16-5

Usage

Uses

Used in Chemical Analysis:
4-METHYL-MORPHOLINEBORANE is used as a reagent for the labeling of oligosaccharides, enabling their quantitative analysis through mass spectrometry. This application is crucial for the study of complex carbohydrates and their roles in biological systems.
Used in Microbiology:
In the field of microbiology, 4-METHYL-MORPHOLINEBORANE is utilized for the analysis of sugar markers associated with Bacillus anthracis spores after culture. This helps in the identification and characterization of these spores, which are significant in the study of anthrax and related diseases.
Used in Carbohydrate Chemistry:
4-METHYL-MORPHOLINEBORANE is employed in the synthesis of sulfated red seaweed galactan derived disaccharide alditol. This application is essential for the development of novel bioactive compounds with potential applications in various industries, including pharmaceuticals and biotechnology.
Used in Analytical Chemistry:
The compound is also used as a reactant for methanolic cleavage, which is a crucial step in the analysis of sulfated galactans from red algae. This process involves reductive hydrolysis and mild methanolysis, followed by high-performance liquid chromatography (HPLC) to separate and identify the resulting products.
Used in Polymer Science:
In the field of polymer science, 4-METHYL-MORPHOLINEBORANE is used in the reductive pyrolysis of carrageenan, a natural polysaccharide found in red seaweed. This process is carried out using high-performance anion-exchange chromatography, which allows for the detailed analysis of the resulting products and their potential applications in various industries.

InChI:InChI=1/C5H13BNO/c1-7(6)2-4-8-5-3-7/h2-6H2,1H3

Upstream product

• 109-02-4 4-methyl-morpholine 
• 19287-45-7 diborane 
• 10294-34-5 boron trichloride 
• 7646-69-7 sodium hydride 
• 121-43-7 Trimethyl borate 
• 542-91-6 H₂SiEt₂ 
• 1609-19-4 diethylchlorosilane 
• 16940-66-2 sodium tetrahydroborate 
• 3651-67-0 N-methylmorpholine hydrochloride 
• 1333-74-0 hydrogen 

Downstream Products

• 109-02-4 4-methyl-morpholine 
• 150-46-9 triethyl borate 
• 1333-74-0 hydrogen 

Relevant academic research and scientific papers

Crown-ether-catalysed synthesis of amine borane and amine trideuterioborane adducts from NaBH4-NaBD4 in ether

Amine borane and amine trideuterioborane adducts have been obtained in good yield by the crown-ether-catalysed reaction of R3N*HCl with NaBH4 and NaBD4 in ether.The absence of isotopic exchange in the reaction with NaBD4 is demonstrated by IR and 11B and

Molecular addition compounds. 9. Effect of structure on the reactivities of representative borane-amine complexes in typical reactions such as hydrolysis, hydroboration, and reduction

A number of borane-amine complexes with widely different structural features in the amine portion was prepared and their reactivities toward typical B-H reactions, such as hydrolysis, hydroboration of 1-octene, and reduction of cyclohexanone, were studied. BH3-amine complexes containing an N-phenyl group are hydrolyzed by neutral hydroxylic solvents, while others require a strong acid medium for the hydrolysis. In hydroboration, BH3-N-phenylamine complexes react rapidly with 1-octene in THF at 25°C, while all other types require refluxing THF or toluene for reaction. Again, BH3-N-phenylamine complexes reduce cyclohexanone in THF at 25°C at reasonable rates, while others require acetic acid solvent or mineral or Lewis acids to achieve the desired reduction. Thus, among such borane-amine addition compounds, the BH3-N-phenylamines emerge as unique hydroborating and reducing agents. The results of the present study provide insights into the mechanisms of the hydroboration and reduction reactions. The rates of hydroboration of alkenes with BH3-amine complexes are inversely related to the stability of the adduct, arguing for a prior dissociation of the adduct, followed by the reaction of BH3 with the alkene. The reduction of cyclohexanone with BH3-amine complex in THF proceeds by an analogous dissociation mechanism. In acetic acid or in the presence of mineral or Lewis acids, a bimolecular attack of the BH3-amine complex on the protonated carbonyl group has been considered to be the most viable mechanistic pathway. However, this does not account for the effect of acids on hydrolytic behavior. Consequently, caution is urged in considering possible interpretation of the acid-enhanced reactions of amine-boranes.

Chemistry of boranes. XV. Synthesis of diborane from boric oxide

A direct synthesis of diborane from boric oxide has been achieved by hydrogenation of the oxide in the presence of aluminum and aluminum trichloride. Very pure diborane is obtained from this reaction in 40-50% conversions at temperatures above 150° and hydrogen pressures of 750 atm. This hydrogenation is believed to proceed through an aluminum chlorohydride intermediate. Amine boranes, aminoboranes, and borazines were obtained directly from boric oxide when the hydrogenation was effected in the presence of secondary or tertiary alkylamines.