15727-80-7

Basic information

• Product Name: Benzoic acid, 4-nitro-, 2-propenyl ester
• Synonyms: Allyl-(4-nitro-benzoat);Benzoic acid,4-nitro,allyl ester;allyl 4-nitrobenzoate;4-Nitro-benzoesaeure-allylester;4-nitro-benzoic acid allyl ester;Allyl p-nitrobenzoate;Benzoic acid,4-nitro-,2-propenyl ester;2-Propenyl 4-nitrobenzoate
• CAS NO: 15727-80-7
• Molecular Formula: C10H9NO4
• Molecular Weight: 207.186
• Mol File: 15727-80-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-nitro-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-nitro-, 2-propenyl ester(15727-80-7)
• EPA Substance Registry System: Benzoic acid, 4-nitro-, 2-propenyl ester(15727-80-7)

Safety Data

• Hazardous Substances Data: 15727-80-7(Hazardous Substances Data)

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 107-18-6 allyl alcohol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 62-23-7 4-nitro-benzoic acid 
• 619-73-8 4-nitrobenzyl chloride 
• 636-98-6 p-nitrobenzene iodide 
• 13939-06-5 molybdenum hexacarbonyl 
• 13277-61-7 p-Nitrobenzoyl bromide 
• 555-16-8 4-nitrobenzaldehdye 
• 107-05-1 3-chloroprop-1-ene 
• 68081-66-3 4-nitro-benzoic acid-(β,β'-dichloro-isopropyl ester) 
• 106-95-6 allyl bromide 
• 619-50-1 4-nitrobenzoic acid methyl ester 

Downstream Products

• 109391-75-5 C₁₆H₁₄Cl₃NO₄Se 
• 36302-35-9 (S)-2-allylcyclohexanone 
• 94-66-6 (R)-2-allylcyclohexanone 
• 111464-55-2 (S)-(+)-2-methyl-2-phenyl-4-pentenylaldehyde 
• 67679-06-5 (R)-(-)-2-methyl-2-phenyl-4-pentenylaldehyde 

Relevant articles and documents

Solar and visible-light active nano Ni/g-C3N4photocatalyst for carbon monoxide (CO) and ligand-free carbonylation reactions

In this study, we investigate the amino and alkoxycarbonylation reaction between various substituted aryl halides, benzyl iodides, and iodocyclohexane with different types of amines and alcohols in the absence of carbon monoxide gas and ligands. Similar reactions are carried out at high temperatures, in the presence of appropriate ligands, stoichiometric amounts of bases, and gaseous carbon monoxide, which endanger the health of organic chemists. We present a novel method that does not utilize ligands, bases, gaseous CO, and special conditions. This procedure is a redox reaction carried out by new economic nano Ni/g-C3N4at room temperature and under visible light. Mo(CO)6was used toin situgenerate CO, to resolve the problems caused by the use of CO gas. This protocol has the ability to be used on a gram scale by using a continuous flow reactor.

Atmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes

A mild, metal-free, atmospheric oxygen-mediated radical hydrothiolation of alkenes (and alkyne) is reported. A variety of sulfur containing motifs including alkanethiols, thiophenols and thioacids undergo an atmospheric oxygen-mediated radical hydrothiolation reaction with a plethora of alkenes in good yield with excellent functional group compatibility, typically with short reaction times to furnish a range of functionalized products. Biomolecules proved tolerant to the conditions and the procedure is robust and easily executable requiring no specialized equipment. Concise mechanistic studies confirm the process proceeds through radical intermediates in a thiol-ene reaction manifold. The methodology offers an efficient “green” approach for thiol-ene mediated “click” ligation and a milder alternative to thermally initiated hydrothiolation processes.

Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: No metal catalysts required

A practical direct method for the direct preparation of esters and thioesters from aldehydes is described. Esters and thioesters were synthesized by oxidative esterification and thioesterification via in situ generated acyl bromide intermediates, which were used to react with various alcohols and thiols. The esterification and thioesterification were readily performed in the presence of dibromoisocyanuric acid in dichloromethane, without any metal catalysts and under mild conditions. By using this reaction protocol, various esters and thioesters were prepared in high yields. This effective method offers a promising approach for the facile esterification and thioesterification of aldehydes.