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N-Sulfinyl-p-toluidine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

15795-42-3

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15795-42-3 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 40, p. 3291, 1975 DOI: 10.1021/jo00910a032

Check Digit Verification of cas no

The CAS Registry Mumber 15795-42-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,7,9 and 5 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 15795-42:
(7*1)+(6*5)+(5*7)+(4*9)+(3*5)+(2*4)+(1*2)=133
133 % 10 = 3
So 15795-42-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H7NOS/c1-6-2-4-7(5-3-6)8-10-9/h2-5H,1H3

15795-42-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methyl-4-(sulfinylamino)benzene

1.2 Other means of identification

Product number -
Other names N-sulfinyl-4-toluidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15795-42-3 SDS

15795-42-3Relevant academic research and scientific papers

Frustrated Lewis pair activation of an N-sulfinylamine: A source of sulfur monoxide

Longobardi, Lauren E.,Wolter, Vanessa,Stephan, Douglas W.

, p. 809 - 812 (2015)

Inter- and intramolecular P/B frustrated Lewis pairs are shown to react with an N-sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine- borane-stabilized sulfur monoxide complexes, and indeed these species act as sources of SO, effecting the oxidation of PPh3 and delivering SO to [RhCl(PPh3)3] and an N-heterocyclic carbene.

Synthesis of benzo-ortho-thiazines S-oxides by diels-alder reaction of N-sulfinylanilines with norbornadiene

Veremeichik,Merabov,Chuiko,Lodochnikova,Plemenkov

, p. 1605 - 1609 (2014/02/14)

From substituted N-sulfinylanilines acting as dienes in the Diels-Alder reaction with norbornadiene S-oxides of benzo-ortho-thiazines were obtained, which were oxidized into the corresponding S,S-dioxides belonging to the class of hybrid thiazinesulfonami

Synthesis of six-membered cyclic sulfonimidamides

Sen, Indira,Kloer, Daniel,Hall, Roger,Pal, Sitaram

, p. 3018 - 3028 (2013/11/06)

A general synthetic route to six-membered cyclic N-aryl- and N-alkyl-substituted sulfonimidamides via an intramolecular ring closure of suitably functionalised acyclic sulfonimidamides is described. The structure of this new ring system was confirmed by v

N-heterocyclic carbene catalysis: Enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines

Jian, Teng-Yue,He, Lin,Tang, Cen,Ye, Song

supporting information; body text, p. 9104 - 9107 (2011/10/13)

Sultam of swing: Both enantiomers of 1,2-thiazetidin-3-one oxides were obtained in very good yields with excellent enantioselectivities when using N-heterocyclic carbene catalysts (see scheme; M.S.=molecular sieves, TBS=tert-butyldimethylsilyl). The products were easily converted into 3-oxo-β-sultams, α-mercapto amides, and β-mercapto amines through oxidation or reduction. Copyright

A-new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

Braverman, Samuel,Cherkinsky, Marina

, p. 487 - 490 (2007/10/03)

The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.

Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Baudin, Jean-Bernard,Commenil, Marie-Gabrielle,Julia, Sylvestre A.,Lorne, Robert,Mauclaire, Laurent

, p. 329 - 350 (2007/10/03)

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.

6?-Cycloadditions of Aryl and New Heteroaryl N-Sulphinylamines With 2,3-Dimethylbuta-1,3-diene: Synthesis, Kinetics, Substituent Effects, Theoretical Calculations, and Reaction Mechanism

Butler, Richard N.,O'Halloran, Gerard A.,Burke, Luke A.

, p. 1855 - 1860 (2007/10/02)

A range of new N-sulphinylamine derivatives of heteroaryl rings, including tetrazoles, oxadiazoles, thiadiazoles, thiazoles, and oxazoles is reported.The influence of the -N=S+-O- group on the n.m.r. spectra of the ring to which it i

NEW FACILE SYNTHESIS OF α-HYDROXYAMIDES:INTERMOLECULAR AND INTRAMOLECULAR CATALYSIS IN THE REACTION OF α-HYDROXYCARBOXYLIC ACIDS WITH N-SULFINYLAMINES.

Shin, Jai Moo,Kim, Yong Hae

, p. 1921 - 1924 (2007/10/02)

α-Hydroxycarboxylic acids (1) reacted with N-sulfinylanilines (2) to give the corresponding α-hydroxyanilides (5) in quantitative yields under mild condition: the reaction appears to involve intermolecular catalysis by the carboxylic acid moiety and intra

NEW FACILE SYNTHESIS OF N-SULFINYLAMINE DERIVATIVES USING N,N'-SULFINYLBISIMIDAZOLE AND N-(CHLOROSULFINYL)IMIDAZOLE

Kim, Yong Hae,Shin, Jai Moo

, p. 3821 - 3824 (2007/10/02)

Treatment of amine derivatives such as amines, sulfonamides, and amides with N,N'-sulfinylbisimidazole (1) and N-(chlorosulfinyl)imidazole (2) in situ respectively gives the corresponding N-sulfinylamine derivatives (3): the latter reaction using N-(chlor

1,2-Thiazines and Related Heterocycles. Part 1. An Investigation of the Cycloadditions of N-Sulphinylanilines with 1,4-Epoxy-1,4-dihydronaphthalene and Other Alkenes

Hanson, Peter,Lewis, Robin J.,Stone, Thomas W.

, p. 1719 - 1724 (2007/10/02)

Evidence is adduced from the character of the alkenes which cycloadd to N-sulphinylanilines and from a kinetic investigation of the reactions of N-sulphinylanilines with 1,4-epoxy-1,4-dihydronaphthalene, examining the effects upon reaction rate of solvent polarity, temperature, and substitution in the N-sulphinylanilines, that the cycloadditions are pericyclic reactions of Diels-Alder type with inverse electron demand.A degree of charge separation in the transition state is indicated but this is small and confined essentially to the sulphinylaniline moiety.

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