15799-66-3

Basic information

• Product Name: triphenyl(2-phenylethenyl)stannane
• CAS NO: 15799-66-3
• Molecular Formula: C₂₆H₂₂Sn
• Molecular Weight: 453.1629
• Mol File: 15799-66-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 509.9°C at 760 mmHg
• Flash Point: 261°C
• Vapor Pressure: 5.18E-10mmHg at 25°C
• CAS DataBase Reference: triphenyl(2-phenylethenyl)stannane(CAS DataBase Reference)
• NIST Chemistry Reference: triphenyl(2-phenylethenyl)stannane(15799-66-3)
• EPA Substance Registry System: triphenyl(2-phenylethenyl)stannane(15799-66-3)

Safety Data

• Hazardous Substances Data: 15799-66-3(Hazardous Substances Data)

Upstream product

• 892-20-6 triphenylstannane 
• 536-74-3 phenylacetylene 

Downstream Products

• 264132-24-3 (1S,2S,3E)-1-[(1S)-1-benzyloxymethoxyethyl]-2-hydroxy-4-phenylbut-3-enyloxyacetic acid tert-butyl ester 
• 16619-61-7 1-phenyl-2-phenylthioethene 
• 34104-05-7 (E)-1-phenyl-2-triphenylgermylethene 
• 894-09-7 iodotriphenylstannane 
• 595-90-4 tetraphenyltin(IV) 
• 95626-30-5 (C₆H₅)3SnC(CH₃)CCH₂ 
• 264132-51-6 C₅₂H₅₃Cl₃O₁₁ 
• 264132-54-9 C₄₄H₄₅Cl₃O₁₀ 
• 264132-57-2 C₄₂H₄₄O₁₀ 
• 264132-20-9 C₄₂H₄₂O₉ 
• 264132-45-8 C₃₈H₃₉Cl₃O₈ 
• 264132-48-1 C₃₀H₃₁Cl₃O₇ 
• 264132-30-1 (2S,3S,6R)-6-[(1S)-1-benzyloxymethoxyethyl]-3-phenyl-3,6-dihydro-2H-pyran-2-carboxylic acid 2,2,2-trichloroethyl ester 
• 264132-27-6 (5S,6S)-5-((S)-1-Benzyloxymethoxy-ethyl)-6-((E)-styryl)-[1,4]dioxan-2-one 

Relevant articles and documents

Efficient syntheses of four stable-isotope labeled (1R)-menthyl (1S,2S)-(+)-2-phenylcyclopropanecarboxylates

Many carbenoid cyclopropanation reactions promoted by chiral catalysts give product mixtures reflecting impressive diastereo- and enantioselectivities. Few provide a single chiral product efficiently. This limitation has been overcome in cyclopropanations of styrene and isotopically labeled styrenes with α-diazoacetates. Convenient syntheses on a 20 g scale of each of four chiral isotopically labeled (1R)-menthyl (1S,2S)-2- phenylcyclopropanecarboxylates (the 1-d-3-13C, 1,(3S)-d2, 1,2,(3S)-d3, and 1,3,3-d3 isotopomers) of better than 99% ee have been realized. The Royal Society of Chemistry 2006.

Palladium Catalyzed Hydrostannylation and Hydrogermylation of Acetylenes

Treatment of acetylenes with Ph3SnH or Ph3GeH in the presence of a catalytic amount of Pd(PPh3)4 provides the corresponding alkenyltriphenylstannanes or alkenyltriphenylgermanes in good yields.