16619-61-7

Basic information

• Product Name: Benzene, [(2-phenylethenyl)thio]-
• CAS NO: 16619-61-7
• Molecular Formula: C14H12S
• Molecular Weight: 212.315
• Mol File: 16619-61-7.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-phenylethenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-phenylethenyl)thio]-(16619-61-7)
• EPA Substance Registry System: Benzene, [(2-phenylethenyl)thio]-(16619-61-7)

Safety Data

• Hazardous Substances Data: 16619-61-7(Hazardous Substances Data)

Upstream product

• 3757-88-8 tributylstannylethynylbenzene 
• 108-98-5 thiophenol 
• 97-94-9 triethyl borane 
• 15799-66-3 trans-β-triphenylstannylstyrene 
• 37891-39-7 trimethylsilane 
• 100-52-7 benzaldehyde 
• 5533-18-6 phenyl dichloromethyl thioether 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 121410-97-7 O-<2,2-bis(phenylthio)-1-phenylethyl> S-methyl dithiocarbonate 
• 97-93-8 triethylaluminum 
• 78839-92-6 2-phenyl-1-(phenylthio)ethenyl diphenyl phosphate 
• 103-64-0 bromostyrene 
• 930-69-8 sodium thiophenolate 
• 42599-24-6 E-styryl iodide 

Downstream Products

• 3019-20-3 isopropylthiobenzene 
• 15325-61-8 3-methyl-1-phenyl-1-butene 
• 605-02-7 1-phenylnaphthalene 
• 2848-29-5 bis(2-phenylethenyl) sulfide 
• 108-98-5 thiophenol 
• 35874-96-5 Phenyl(phenylthio)acetaldehyd 
• 65-85-0 benzoic acid 
• 882-33-7 diphenyldisulfane 
• 588-59-0 stilbene 
• 139-66-2 diphenyl sulfide 
• 108-88-3 toluene 
• 95-15-8 Benzo[b]thiophene 
• 71-43-2 benzene 
• 38509-16-9 1,1-dimethoxy-2-(phenylthio)-2-phenylethane 

Relevant articles and documents

Acetylene and terminal alkyne complexes of copper(i) supported by fluorinated pyrazolates: Syntheses, structures, and transformations

Trinuclear {μ-[3,5-(CF3)2Pz]Cu}3 reacts with acetylene to produce the 2:1 copper(i) acetylene complex, Cu4(μ-[3,5-(CF3)2Pz])4(μ-HCCH)2. Related Cu4(μ-[4-Br-3,5-(CF3)2Pz])4(μ-HCCH)2 and Cu4(μ-[4-Cl-3,5-(CF3)2Pz])4(μ-HCCH)2 have also been isolated using the corresponding copper(i) pyrazolate and acetylene. The 1:1 adducts Cu2(μ-[3,5-(CF3)2Pz])2(HCCH)2 and Cu2(μ-[4-Br-3,5-(CF3)2Pz])2(HCCH)2 are significantly less stable to the acetylene loss and can be observed in solution at low temperatures under excess acetylene. The X-ray crystal structures of 2:1 and 1:1 complexes, Cu4(μ-[3,5-(CF3)2Pz])4(μ-HCCH)2 and Cu2(μ-[4-Br-3,5-(CF3)2Pz])2(HCCH)2 are reported. Raman data show a reduction in CC stretching frequency by about ～340 and ～163 cm-1 in the 2:1 and 1:1 Cu(i)/acetylene complexes, respectively, from that of the free acetylene. Copper(i) pyrazolate complexes of the terminal alkynes, phenylacetylene, 1,8-nonadiyne, and 1,7-octadiyne are also reported. They form adducts involving one copper atom on each alkyne moiety. The {μ-[3,5-(CF3)2Pz]Cu}3 is also a very versatile and competent catalyst for alkyne transformations as evident from its ability to catalyze the alkyne C(sp)-H bond carboxylation chemistry with CO2, azide-alkyne cycloadditions leading to 1,2,3-triazoles including the use of acetylene itself as a substrate, and thiol addition to phenylacetylene affording vinyl sulfides.

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Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

Gem-Heterosubstituted (stannyl)methylsilanes as synthetic equivalents of functionalized α-stannyl(methyl) anions

α-Heterosubstituted silyl derivatives, such as phenylthio-, phenylseleno- and benzotriazolyl-stannyl silanes, react with aldehydes under tetra-n-butylammonium fluoride (TBAF) catalysis, leading to α-substituted-βhydroxy stannanes, able to behave as precursors of Z- and E-olefins, generated by deoxystannylation. This reactivity shows the capability of such heterosubstituted silanes to act as masked carbanions through a mild functionalization of the carbon-silicon bond.