15810-14-7

Basic information

• Product Name: 9,10-DIETHYLPHENANTHRENE
• Synonyms: 9,10-DIETHYLPHENANTHRENE
• CAS NO: 15810-14-7
• Molecular Formula: C₁₈H₁₈
• Molecular Weight: 234.34
• Mol File: 15810-14-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 384.8°C at 760 mmHg
• Flash Point: 179.7°C
• Appearance: /
• Density: 1.049g/cm³
• Vapor Pressure: 8.84E-06mmHg at 25°C
• Refractive Index: 1.645
• CAS DataBase Reference: 9,10-DIETHYLPHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-DIETHYLPHENANTHRENE(15810-14-7)
• EPA Substance Registry System: 9,10-DIETHYLPHENANTHRENE(15810-14-7)

Safety Data

• Hazardous Substances Data: 15810-14-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H18/c1-3-13-14(4-2)16-10-6-8-12-18(16)17-11-7-5-9-15(13)17/h5-12H,3-4H2,1-2H3

Upstream product

• 17918-49-9 9-Brom-10-ethyl-phenanthren 
• 75-03-6 ethyl iodide 
• 5561-92-2 1-(2-methoxyphenyl)propan-1-one 
• 85-01-8 phenanthrene 
• 573-17-1 9-bromophenanthrene 
• 85-44-9 phthalic anhydride 
• 928-49-4 hex-3-yne 
• 591-50-4 iodobenzene 
• 221692-50-8 α-phenyl-α,α-diethylacetaldehyde 
• 95127-86-9 1,2,3,4,5,8-Hexahydro-3-oxo-9,10-diethyl-phenanthren 
• 97079-65-7 3-Methoxy-9,10-diaethylphenanthren 
• 3674-75-7 9-ethylphenanthrene 
• 103441-58-3 1-(2-iodophenyl)propan-1-one 
• 609-67-6 2-Iodobenzoyl chloride 

Relevant articles and documents

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Phenanthrene Synthesis by Palladium(II)-Catalyzed γ-C(sp2)-H Arylation, Cyclization, and Migration Tandem Reaction

Phenanthrene is an important structural motif in chemistry and materials science, and many synthetic routes have been developed to construct its skeleton. However, synthesis of unsymmetric phenanthrenes remains a challenge. Here, an efficient one-pot tandem reaction for the preparation of phenanthrenes via sequential γ-C(sp2)-H arylation, cationic cyclization, dehydration, and 1,2-migration was developed. A wide range of symmetric and unsymmetric phenanthrenes with diversified functional groups were synthesized with good to excellent yields.

Synthesis of multiply substituted polycyclic aromatic hydrocarbons by iridium-catalyzed annulation of ring-fused benzocyclobutenol with alkyne through C-C bond cleavage

The first iridium-catalyzed intermolecular cyclization between alkynes and ring-fused benzocyclobutenols (RBCB) through C-C bond cleavage is described. A variety of elusive polycyclic aromatic hydrocarbons (PAHs) with multiple substituents are obtained in good yields under mild conditions. This procedure provides a unique and expeditious tool for the synthesis of PAHs. Expanding the family: The iridium-catalyzed intermolecular cyclization between ring-fused benzocyclobutenols and alkynes through C-C bond cleavage is described. A variety of elusive polycyclic aromatic hydrocarbons (PAHs) with multiple substituents are obtained in good yields under mild conditions. The transformation exhibits good functional-group tolerance and regioselectivity.