1587-07-1 Usage
Description
1-Allyl-2-chlorobenzene, also known as Allyl Chlorobenzene, is a low-density, colorless to light yellow liquid chemical compound with aromatic and unsaturated aliphatic moieties and a chlorine substitution. It has the chemical formula C9H9Cl and a molecular weight of 154.62 g/mol. 1-ALLYL-2-CHLOROBENZENE is stable under normal conditions but may decompose upon heating, releasing toxic gases such as hydrogen chloride and carbon monoxide. Due to its flammability and potential to cause skin and eye irritation, it should be handled with caution.
Uses
Used in Pharmaceutical Industry:
1-Allyl-2-chlorobenzene is used as an intermediate in the synthesis of various pharmaceutical compounds. Its aromatic and unsaturated aliphatic moieties, along with the chlorine substitution, make it a versatile building block for the development of new drugs.
Used in Organic Synthesis:
1-Allyl-2-chlorobenzene is used as a key component in the synthesis of organic compounds, particularly in the pharmaceutical industry. Its unique structure allows for various chemical reactions, enabling the creation of a wide range of molecules with potential applications in medicine and other fields.
Check Digit Verification of cas no
The CAS Registry Mumber 1587-07-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,8 and 7 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1587-07:
(6*1)+(5*5)+(4*8)+(3*7)+(2*0)+(1*7)=91
91 % 10 = 1
So 1587-07-1 is a valid CAS Registry Number.
InChI:InChI=1/C9H9Cl/c1-2-5-8-6-3-4-7-9(8)10/h2-4,6-7H,1,5H2
1587-07-1Relevant articles and documents
Carbonylative Transformation of Allylarenes with CO Surrogates: Tunable Synthesis of 4-Arylbutanoic Acids, 2-Arylbutanoic Acids, and 4-Arylbutanals
Wu, Fu-Peng,Li, Da,Peng, Jin-Bao,Wu, Xiao-Feng
supporting information, p. 5699 - 5703 (2019/08/01)
In this Communication, procedures for the selective synthesis of 4-arylbutanoic acids, 2-arylbutanoic acids, and 4-arylbutanals from the same allylbenzenes have been developed. With formic acid or TFBen as the CO surrogate, reactions proceed selectively and effectively under carbon monoxide gas-free conditions.
Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis
Akram, Manjur O.,Mali, Pramod S.,Patil, Nitin T.
supporting information, p. 3075 - 3078 (2017/06/23)
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.
Phosphazene base-promoted halogen-zinc exchange reaction of aryl iodides using diethylzinc
Ueno, Masahiro,Wheatley, Andrew E. H.,Kondo, Yoshinori
, p. 3549 - 3550 (2008/09/19)
The use of catalytic t-Bu-P4 base dramatically improved the performance of halogen-zinc exchange of aryl iodides, and the arylzinc derivatives were functionalized under copper-free reaction conditions. The Royal Society of Chemistry 2006.