1588-56-3Relevant articles and documents
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Closs et al.
, p. 4985 (1962)
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Picosecond radical kinetics. Fast ring openings of secondary and tertiary trans-2-phenylcyclopropylcarbinyl radicals
Choi,Toy,Newcomb
, p. 8609 - 8613 (2007/10/03)
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Stereoselective Carbon-Carbon Bond-Forming Reaction of 1,1-Dibromocyclopropanes via 1-Halocyclopropylzincates
Harada, Toshiro,Katsuhira, Takeshi,Hattori, Kazuhiro,Oku, Akira
, p. 2958 - 2965 (2007/10/02)
Lithium trialkylzincates react efficiently with 1,1-dibromocyclopropanes 5 to give the corresponding alkylation products 7 nonstereoselectively.The reaction proceeds through a 1,2-alkyl migration of the intermediately formed zincate carbenoid 3 in an inve