15901-42-5

Basic information

• Product Name: 3,3,5-TRIMETHYLCYCLOHEXYLAMINE
• Synonyms: 3,3,5-TRIMETHYLCYCLOHEXYLAMINE 99+% GC;3,3,5-TRIMETHYLCYCLOHEXYLAMINE;3,3,5-TRIMETHYLCYCLOHEXANAMINE;3,3,5-trimethyl-cyclohexanamin;3,3,5-trimethylcyclohexylamine,mixtureofcisandtrans;3,5,5-Trimethylcyclohexylamine;3,3,5-Trimethylcyclohexylamine, mixture of cis and trans,99+%;Cyclohexanamine, 3,3,5-trimethyl-
• CAS NO: 15901-42-5
• Molecular Formula: C₉H₁₉N
• Molecular Weight: 141.25
• EINECS: 240-041-3
• Mol File: 15901-42-5.mol
• Article Data: 10

Chemical Properties

• Melting Point: -79.9°C
• Boiling Point: 177 °C
• Flash Point: 60°C
• Appearance: /
• Density: 0,84 g/cm3
• Refractive Index: 1.4520-1.4560
• PKA: 10.69±0.70(Predicted)
• CAS DataBase Reference: 3,3,5-TRIMETHYLCYCLOHEXYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,5-TRIMETHYLCYCLOHEXYLAMINE(15901-42-5)
• EPA Substance Registry System: 3,3,5-TRIMETHYLCYCLOHEXYLAMINE(15901-42-5)

Safety Data

• Statements: 10-34
• Safety Statements: 26-36/37/39
• RIDADR: 2734
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 15901-42-5(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C9H19N/c1-7-4-8(10)6-9(2,3)5-7/h7-8H,4-6,10H2,1-3H3

Upstream product

• 2157-58-6 3,5,5-trimethyl-cyclohex-2-enone oxime 
• 37690-43-0 trans-3.3.5-Trimethylcyclohexanol-tosylat 
• 37694-11-4 3,3,5-trimethylcyclohexanone oxime 
• 134734-56-8 (E)-O-acetyl 3,5,5-trimethyl-2-cyclohexene-1-one oxime 
• 7027-11-4 isophoronenitrile 
• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 
• 3968-96-5 (E)-3,5,5-trimethylcyclohex-2-en-1-one oxime 
• 77287-34-4 formamide 
• 873-94-9 dihydroisophorone 
• 540-69-2 ammonium formate 

Relevant articles and documents

Production of Primary Amines by Reductive Amination of Biomass-Derived Aldehydes/Ketones

Transformation of biomass into valuable nitrogen-containing compounds is highly desired, yet limited success has been achieved. Here we report an efficient catalyst system, partially reduced Ru/ZrO2, which could catalyze the reductive amination of a variety of biomass-derived aldehydes/ketones in aqueous ammonia. With this approach, a spectrum of renewable primary amines was produced in good to excellent yields. Moreover, we have demonstrated a two-step approach for production of ethanolamine, a large-market nitrogen-containing chemical, from lignocellulose in an overall yield of 10 %. Extensive characterizations showed that Ru/ZrO2-containing multivalence Ru association species worked as a bifunctional catalyst, with RuO2 as acidic promoter to facilitate the activation of carbonyl groups and Ru as active sites for the subsequent imine hydrogenation.

Tetracyclic benzimidazole derivatives and combinatorial libraries thereof

The present invention relates to novel tetracyclic benzimidazole derivative compounds of the following formula: wherein R1to R10have the meanings described in here. The invention further relates to combinatorial libraries containing two or more such compounds, as well as methods of preparing tetracyclic benzimidazole derivative compounds.

Simple catalytic synthesis of 3,3,5-trimethylcyclohexylamine

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