159783-14-9

Upstream product

• 531-37-3 2-methoxyphenyl benzoate 
• 98-88-4 benzoyl chloride 
• 90-05-1 2-methoxy-phenol 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 623550-32-3 (1R,3R,3aS,4S,5R,6R,7R,7aR)-4-acetoxy-3-acetoxymethyl-7-tert-butyldimethylsiloxy-1-[(1S)-acetoxy[4-methoxy-3-(methoxymethoxy)phenyl]methyl]-5,6-(isopropylidenedioxy)octahydroindene 
• 623550-26-5 (1R,3R,3aS,4S,5R,6R,7R,7aR)-7-tert-butyldimethylsiloxy-1-[(1S)-hydroxy[4-methoxy-3-(methoxymethoxy)phenyl]methyl]-3-hydroxymethyl-5,6-(isopropylidenedioxy)octahydroindene-4-ol 
• 623550-65-2 (2S,2aS,4R,4aR,5R,6R,7R,7aS,7bR)-5-tert-butyldimethylsiloxy-4-[(R)-hydroxy-[4-methoxy-3-(methoxymethoxy)phenyl]methyl]-6,7-(O-isopropylidenedioxy)decahydroindeno[7,1-bc]furan-2-ol 
• 623550-19-6 (2S,2aS,4R,4aR,5R,6R,7R,7aS,7bR)-5-tert-butyldimethylsiloxy-4-[(S)-hydroxy-[4-methoxy-3-(methoxymethoxy)phenyl]methyl]-6,7-(O-isopropylidenedioxy)decahydroindeno[7,1-bc]furan-2-ol 
• 623550-22-1 (1R,3R,3aR,4R,5R,6R,7S,7aR)-4-tert-butyldimethylsiloxy-7-hydroxy-3-[(1S)-hydroxy[4-methoxy-3-(methoxymethoxy)phenyl]methyl]-5,6-(isopropylidenedioxy)octahydroindene-1-carbaldehyde 
• 623550-33-4 (1S,3R,3aS,4S,5R,6R,7R,7aR)-7-tert-butyldimethylsiloxy-3-hydroxymethyl-5,6-O-isopropylidenedioxy-1-[4-methoxy-3-(methoxymethoxy)benzyl]octahydroinden-4-ol 
• 623550-48-1 (3aR,4R,4aR,5S,7S,7aS,8aR)-5-(3-acetoxy-4-methoxybenzyl)-4-tert-butyldimethylsiloxy-8-methylene-7-(vinyl)octahydroindeno[5,6-d,1,3]dioxol-2-thione 
• 623550-05-0 (1S,3S,3aS,4S,5R,6R,7R,7aR)-7-tert-butyldimethylsiloxy-5,6-O-isopropylidenedioxy-1-[4-methoxy-3-(methoxymethoxy)benzyl]-4-methylene-3-(vinyl)octahydroindene 
• 623550-45-8 (1S,3S,3aR,4R,5R,6R,7aS)-3-(3-acetoxy-4-methoxybenzyl)-4-tert-butyldimethylsiloxy-7-methylene-1-(vinyl)octahydroindene-5,6-diol 
• 623550-37-8 (1R,3R,3aR,4R,5R,6S,7R)-4-tert-butyldimethylsiloxy-5,6-O-isopropylidenedioxy-3-[4-methoxy-3-(methoxymethoxy)benzyl]-7-oxooctahydroindene-1-carbaldehyde 
• 623550-42-5 (1S,3S,3aR,4R,5R,6R,7aS)-4-tert-butyldimethylsiloxy-3-(3-hydroxy-4-methoxybenzyl)7-methylene-1-(vinyl)octahydroindene-5,6-diol 
• 623550-52-7 (1S,3S,3aR,4S,7aS)-3-(3-acetoxy-4-methoxybenzyl)-4-tert-butyldimethylsiloxy-7-methylene-1-vinyl-1,2,3,3a,7,7a-hexahydroindene 
• 623550-59-4 (1S,3S,3aR,4S,7aS)-3-(3-dichloroacetoxy-4-methoxybenzyl)-1,2,3,3a,7,7a-hexahydro-7-methylene-1-(vinyl)inden-4-ol 
• 623550-56-1 (1S,3S,3aR,4S,7aS)-3-(3-hydroxy-4-methoxybenzyl)-7-methylene-1-vinyl-1,2,3,3a,7,7a-hexahydroindene-4-ol 

Relevant academic research and scientific papers

Visible-light-triggered direct benzoyloxylation of electron-rich arenes at room temperature without chelation assistance

A RuII photocatalytic method was developed for the direct mono-benzoyloxylation of electron-rich aromatic and heteroaromatic systems even with an excess amount of benzoyl peroxide. The reaction was conducted at room temperature under visible light. The direct ArC-H benzoyloxylations occur without the assistance of any directing groups and can also tolerate various functional groups that have already shown diverse reactivities in transition-metal catalysis.

Total Synthesis and Absolute Configuration of Otteliones A and B, Novel and Potent Antitumor Agents from a Freshwater Plant

(Matrix presented) The first enantioselective total synthesis of otteliones A and B, biologically important and structurally novel natural products, has been successfully achieved. This total synthesis fully confirms the absolute configuration of these natural products.

COMPOUNDS CONTAINING PHENYL LINKED TO ARYL OR HETEROARYL BY AN ALIPHATIC- OR HETEROATOM-CONTAINING LINKING GROUP

This invention is directed to the pharmaceutical use of phenyl compounds, which are linked to an aryl moiety by various linkages, for inhibiting tumor necrosis factor. The invention is also directed to the compounds, their preparation and pharmaceutical compositions containing these compounds. Furthermore, this invention is directed to the pharmaceutical use of the compounds for inhibiting cyclic AMP phosphodiesterase

Compounds containing phenyl linked to aryl or heteroaryl by an aliphatic-or heteroatom-containing linking group

This invention is directed to the pharmaceutical use of phenyl compounds, which are linked to an aryl moiety by various linkages, for inhibiting tumor necrosis factor. The invention is also directed to the compounds, their preparation and pharmaceutical compositions containing these compounds. Furthermore, this invention is directed to the pharmaceutical use of the compounds for inhibiting cyclic AMP phosphodiesterase.