15984-93-7

Basic information

• Product Name: TMS DL-valine
• Synonyms: TMS DL-valine;Trimethylsilyl DL-valine
• CAS NO: 15984-93-7
• Molecular Formula: C₁₁H₂₇NO₂Si₂
• Molecular Weight: 261.51
• Mol File: 15984-93-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 236.4±23.0 °C(Predicted)
• Appearance: /
• Density: 0.887±0.06 g/cm3(Predicted)
• PKA: 9.59±0.70(Predicted)
• CAS DataBase Reference: TMS DL-valine(CAS DataBase Reference)
• NIST Chemistry Reference: TMS DL-valine(15984-93-7)
• EPA Substance Registry System: TMS DL-valine(15984-93-7)

Safety Data

• Hazardous Substances Data: 15984-93-7(Hazardous Substances Data)

Upstream product

• 516-06-3 D,L-valine 
• 996-50-9 N,N-diethyl-1,1,1-trimethylsilanamine 
• 75-77-4 chloro-trimethyl-silane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 7677-24-9 trimethylsilyl cyanide 
• 43112-38-5 3-(trimethylsilyl)-2-oxazolidinone 
• 33419-01-1 H-Val-OH p-toluenesulfonic acid salt 

Downstream Products

• 79137-52-3 N-(1-Butylcyclohexylcarbonyl)-2-(3-oxobutyl)valin 
• 80875-24-7 DL-Val-NHi-Pr 
• 84860-35-5 N-phenylcarbamoyl-DL-valine ; inactive α-(ω-phenyl-ureido)-isovaleric acid 
• 79137-51-2 N-(1-Butylcyclohexylcarbonyl)valin 
• 2816-12-8 4-isopropyl-2,5-oxazolidinedione 
• 53870-94-3 Z-Gly-Val-OH 

Relevant articles and documents

ENANTIOMERIC QUANTIFICATIONS OF AMINO ACIDS THROUGH THEIR Nα-ACYL AMIDES BY GAS CHROMATOGRAPHY.

Apparent separation of 1.1 or higher on Chiralsil Val III can be obtained for Nα-acyl N-alkyl aminoacid amides allowing the use of short capillary gas chromatographic columns.A clean derivatization protocol without racemization is described, proceding through the NCA derivatives that are prepared from "in situ" silylated amino acids with trimethylsilyl cyanide.