15989-98-7

Upstream product

• 1076-44-4 pentafluorophenyl lithium 
• 10108-64-2 cadmium(II) chloride 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 15967-66-5 Cd-bis-pentafluorbenzoat 
• 344-04-7 bromopentafluorobenzene 
• 1735-62-2 Bromo-bis-(pentafluorphenyl)-thallium(III) 
• 7440-43-9 cadmium 
• 18064-83-0 tetrakis(pentafluorophenyl)tellurium(IV) 

Downstream Products

• 75822-05-8 pentafluorphenylbrom(V)tetrafluorid 
• 328379-54-0 bis(pentafluorophenyl)xenon 
• 179637-91-3 bis(triphenylphosphin)iminium-tetrakis(pentafluorphenyl)gallat 
• 31569-56-9 tris-(pentafluoro phenyl) indane 
• 10108-64-2 cadmium(II) chloride 
• 1534-67-4 pentafluorophenyl(phenyl)mercury 
• 7790-79-6 cadmium(II) fluoride 
• 81607-30-9 2,3,4,5,6-pentafluorophenyldifluorobromane 
• 52393-47-2 2-(Pentafluorphenyl)-acetophenon 
• 24043-89-8 1,2-bis(pentafluorophenyl)ethanone 

Relevant academic research and scientific papers

Syntheses and properties of tetrakis(pentafluorophenyl)tellurium, Te(C6F5)4, and related compounds - (See abstract)

Te(C6F5)4 was prepared from the reactions of TeCl4 or Te(C6F5)2Cl2 with Grignard reagents or AgC6F5 in moderate to good yields. Substitution reactions with Me3SiX (X = Cl, Br, OSO2CF3), with equimolar amounts of Br2, with AgNO3 and with H[BF4] or BF3·OEt2 yielded the Te(C6F5)3X derivatives (X = Cl, Br, OSO2CF3, NO3, BF4). Oxidation reactions of Cd, Hg, and Pd0 complexes led to Te(C6F5)2 and the corresponding bis(pentafluorophenyl) derivatives M(C6F5)2 (M = Cd, Hg, Pd) and with InBr to In(C6F5)2Br. From very slow hydrolysis of Te(C6F5)4 the oxide Te(C6F5)2O was prepared. The thermal decomposition, the NMR and mass spectra of the partially new compounds are discussed. The crystal structures of Te(C6F5)3Br (monoclinic, P21/a, Z = 4), [Te(C6F5)3][OSO2CF3] (monoclinic, P21/n, Z = 16) and [Te(C6F5)2O]2 (triclinic, P1, Z = 2) were determined.

Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements

Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.