24043-89-8Relevant academic research and scientific papers
Diastereoselective synthesis of pinacols from aromatic aldehydes using the system pentacarbonyliron-hexamethylphosphoric triamide. Dual reactivity of pentafluorobenzaldehyde
Terent'ev,Vasil'eva,Chakhovskaya,Mysova,Kochetkov
, p. 518 - 521 (2007)
The system Fe(CO)5-HMPA effectively promotes diastereoselective reductive dimerization of aromatic aldehydes to the corresponding pinacols having preferentially or exclusively dl configuration. In the reaction with pentafluorobenzaldehyde, the product structure strongly depends on the presence of traces of moisture in the reaction system. Nauka/Interperiodica 2007.
Pentafluorophenyl carbonyl compounds in the Reformatsky-type reactions promoted with Fe(CO)5-based metal complex systems
Terent'ev,Vasil'eva,Chahovskaya,Mysova,Hambardzumyan,Kochetkov
, p. 669 - 673 (2008/12/22)
Iron pentacarbonyl is an effective promoter for additions of halogenated acid esters and nitriles to pentafluorophenyl carbonyl compounds 1, 4, and 5 by the Reformatsky-type reaction and reductive coupling of compound 1. The electron-withdrawing character
