31569-56-9Relevant academic research and scientific papers
On the chemistry of fluoroorgano derivatives of group 13 elements. 2: Synthesis and characterization of the 1:1-adducts of In(C6F5)3 with acetonitrile, glyme, and DMAP (DMAP = 4-(N,N-dimethylamino)-pyridine), and [PNP][In(C6F5)4](PNP = bis(triphenylphosphinanyliden)-immonium)
Choi, Zel-Ho,Tyrra, Wieland,Adam, Arnold
, p. 1287 - 1292 (2008/10/08)
In(C6F5)3 · CH3CN and In(C6F5)3 · glyme were synthesized from InCl3 and Cd(C6F5)2 in CH3CN or glyme in 43% and 35% yield, respectively. Replacement of CH3CN or (C2H5)2O by DMAP yielded the corresponding 1:1-adduct. [PNP][In(C6F5)4] was best prepared from the corresponding cesium salt which was best synthesized from the reaction of stoichiometric amounts of In(C6F5)3 · CH3CN, (CH3)3 SiC6F5 and CsF in good yield. _[PNP][In(C6F5)4] crystallizes in the triclinic space group P1, a = 1104.9(4) pm, b = 1442.4(6) pm, c = 1833.8(8) pm, α = 110.87(2)°, β = 92.04(3)°, γ = 96.55(3)°, Z = 2.
Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements
Deacon,Parrott
, p. 287 - 295 (2008/10/08)
Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.
