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1599-47-9

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1599-47-9 Usage

Chemical Properties

Clear colorless liquid

Synthesis Reference(s)

Synthesis, p. 705, 1974 DOI: 10.1055/s-1974-23406

Check Digit Verification of cas no

The CAS Registry Mumber 1599-47-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,9 and 9 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1599-47:
(6*1)+(5*5)+(4*9)+(3*9)+(2*4)+(1*7)=109
109 % 10 = 9
So 1599-47-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H18O2/c1-4-5-6-7-8(9-2)10-3/h8H,4-7H2,1-3H3

1599-47-9 Well-known Company Product Price

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  • Alfa Aesar

  • (A18824)  Hexanal dimethyl acetal, 98%   

  • 1599-47-9

  • 25g

  • 214.0CNY

  • Detail
  • Alfa Aesar

  • (A18824)  Hexanal dimethyl acetal, 98%   

  • 1599-47-9

  • 100g

  • 741.0CNY

  • Detail
  • Aldrich

  • (547174)  1,1-Dimethoxyhexane  98%

  • 1599-47-9

  • 547174-25G

  • 203.58CNY

  • Detail

1599-47-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name HEXANAL DIMETHYL ACETAL

1.2 Other means of identification

Product number -
Other names n-Hexanal dimethylacetal

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1599-47-9 SDS

1599-47-9Relevant articles and documents

One-pot Synthesis of Acetals by Tandem Hydroformylation-acetalization of Olefins Using Heterogeneous Supported Catalysts

Li, Xiao,Qin, Tingting,Li, Liusha,Wu, Bo,Lin, Tiejun,Zhong, Liangshu

, p. 2638 - 2646 (2021/01/05)

Abstract: A green route for one?pot synthesis of acetals by tandem hydroformylation?acetalization of olefins using supported Rh?based?catalysts was developed. Experimental results demonstrated that suitable Rh loading (1 wt%) with appropriate reaction temperature (120?°C) and reaction time (8?h) were favorable for the formation of acetals, and a high acetals selectivity of 94.6% was achieved. More importantly, the selectivity to valuable linear products was enhanced in this tandem catalysis. Based on the catalytic mechanism study, highly dispersed RhOx nanoparticles and abundant acid sites on the supports were responsible for the hydroformylation and acetalization, respectively. Graphical abstract: One-pot synthesis of acetals directly from olefins with high selectivity was achieved over heterogeneous bifunctional catalysts via tandem hydroformylation-acetalization. [Figure not available: see fulltext.]

Hyper-Cross-Linked Polyacetylene-Type Microporous Networks Decorated with Terminal Ethynyl Groups as Heterogeneous Acid Catalysts for Acetalization and Esterification Reactions

Sekerová, Lada,Lhotka, Miloslav,Vysko?ilová, Eli?ka,Faukner, Tomá?,Slováková, Eva,Brus, Ji?í,?erveny, Libor,Sedlá?ek, Jan

, p. 14742 - 14749 (2018/09/25)

Heterogeneous catalysts based on materials with permanent porosity are of great interest owing to their high specific surface area, easy separation, recovery, and recycling ability. Additionally, porous polymer catalysts (PPCs) allow us to tune catalytic activity by introducing various functional centres. This study reports the preparation of PPCs with a permanent micro/mesoporous texture and a specific surface area SBET of up to 1000 m2 g?1 active in acid-catalyzed reactions, namely aldehyde and ketone acetalization and carboxylic acid esterification. These PPC-type conjugated hyper-cross-linked polyarylacetylene networks were prepared by chain-growth homopolymerization of 1,4-diethynylbenzene, 1,3,5-triethynylbenzene and tetrakis(4-ethynylphenyl)methane. However, only some ethynyl groups of the monomers (from 58 to 80 %) were polymerized into the polyacetylene network segments while the other ethynyl groups remained unreacted. Depending on the number of ethynyl groups per monomer molecule and the covalent structure of the monomer, PPCs were decorated with unreacted ethynyl groups from 3.2 to 6.7 mmol g?1. The hydrogen atoms of the unreacted ethynyl groups served as acid catalytic centres of the aforementioned organic reactions. To the best of our knowledge, this is first study describing the high activity of hydrogen atoms of ethynyl groups in acid-catalyzed reactions.

Enantioselective copper(I/II)-catalyzed conjugate addition of nitro esters to β,γ-unsaturated α-ketoesters

Zhang, Sheng,Xu, Kun,Guo, Fengfeng,Hu, Yanbin,Zha, Zhenggen,Wang, Zhiyong

supporting information, p. 979 - 982 (2014/02/14)

A highly enantioselective Michael addition of nitroacetates to β,γ-unsaturated α-ketoesters was developed by using chiral copper catalysts. The Michael addition products can be obtained in high yields with up to 99 % ee. With these densely functionalized products, the chiral cyclic nitrones, which are important synthetic intermediates, can be obtained in one step. Copyright

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