1605-56-7

Basic information

• Product Name: Phosphine, diphenyl(trifluoromethyl)-
• CAS NO: 1605-56-7
• Molecular Formula: C13H10F3P
• Molecular Weight: 254.191
• Mol File: 1605-56-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Phosphine, diphenyl(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, diphenyl(trifluoromethyl)-(1605-56-7)
• EPA Substance Registry System: Phosphine, diphenyl(trifluoromethyl)-(1605-56-7)

Safety Data

• Hazardous Substances Data: 1605-56-7(Hazardous Substances Data)

Upstream product

• 75-63-8 Bromotrifluoromethane 
• 1079-66-9 chloro-diphenylphosphine 
• 2283-11-6 hexaethylphosphoric triamide 
• 119-61-9 benzophenone 
• 129922-46-9 triphenyl(trifluoromethyl)phosphonium trifluoromethanesulfonate 
• 829-85-6 diphenylphosphane 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 4559-70-0 Diphenylphosphine oxide 
• 1961266-44-3 2,8-difluoro-5-(trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate 
• 2314-97-8 iodotrifluoromethane 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 
• 887144-94-7 Togni's reagent II 
• 887144-97-0 Togni's reagent 
• 4376-01-6 sodium diphenylphosphide 

Downstream Products

• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 791-28-6 Triphenylphosphine oxide 
• 72450-51-2 bis(triphenyl)oxodiphosphonium trifluoromethanesulfonate salt 
• 129922-46-9 triphenyl(trifluoromethyl)phosphonium trifluoromethanesulfonate 
• 1270027-50-3 [AuCl(PPh₂(CF₃))] 
• 103189-74-8 bis(diphenyltrifluoromethylphosphine)dichloroplatinum(II) 
• 16284-64-3 diphenyltrifluoromethylphosphine oxide 

Relevant articles and documents

Visible-Light-Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations

The sigma (σ)-hole effect has emerged as a promising tool to construct novel architectures endowed with new properties. A simple yet effective strategy for the generation of monofluoromethyl radicals is a continuing challenge within the synthetic communit

Siladifluoromethylation and Deoxo-trifluoromethylation of PV-H Compounds with TMSCF3: Route to PV-CF2- Transfer Reagents and P-CF3 Compounds

A method for siladifluoromethylation of dialkyl phosphonates and secondary phosphine oxides with TMSCF3 to produce nucleophilic PV-CF2- transfer reagents is disclosed, with multigram scale reactions included. Condition-dependent divergent reactivity under the established conditions is demonstrated by the formation of trifluoromethylphosphines. Both one-pot transformations are operationally simple and employ inexpensive materials. Mechanistic investigations suggest the divergent reactivity originates from a common intermediate, with Li+ concentration directing the chemoselectivity.

Borazine-CF3? Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation

A fluoroform-derived borazine CF3? transfer reagent is used to effect rapid nucleophilic reactions in the absence of additives, within minutes at 25 °C. Inorganic electrophiles spanning seven groups of the periodic table can be trifluoromethylated in high yield, including transition metals used for catalytic trifluoromethylation. Organic electrophiles included (hetero)arenes, enabling C?H and C?X trifluoromethylation reactions. Mechanistic analysis supports a dissociative mechanism for CF3? transfer, and cation modification afforded a reagent with enhanced stability.