160596-45-2

Basic information

• Product Name: Benzenemethanol, a-methyl-a-[2-[2-(1-methylethyl)-1,3-dioxolan-2-yl]ethenyl]-, (E)-
• CAS NO: 160596-45-2
• Molecular Formula: C16H22O3
• Molecular Weight: 262.349
• Mol File: 160596-45-2.mol

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-methyl-a-[2-[2-(1-methylethyl)-1,3-dioxolan-2-yl]ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-methyl-a-[2-[2-(1-methylethyl)-1,3-dioxolan-2-yl]ethenyl]-, (E)-(160596-45-2)
• EPA Substance Registry System: Benzenemethanol, a-methyl-a-[2-[2-(1-methylethyl)-1,3-dioxolan-2-yl]ethenyl]-, (E)-(160596-45-2)

Safety Data

• Hazardous Substances Data: 160596-45-2(Hazardous Substances Data)

Upstream product

• 58953-14-3 (E)-isopropyl 2-chlorovinyl ketone 
• 98-86-2 acetophenone 
• 160596-30-5 (E)-2-(2-chlorovinyl)-2-(isopropyl)-1,3-dioxolane 

Relevant articles and documents

Ketalised α- and β-lithiated α,β-unsaturated ketones: New masked acylvinyl anion equivalents

The reaction of chloroketals 1, 5 and 10 with an excess of lithium powder and a catalytic amount of DTBB (4-5%) in THF at -78 or -90°C leads to the corresponding functionalised organolithium compounds 2, 6 and 11, respectively, resulting from a chlorine/l

2-Substituted (E)-2-(2-Lithioethenyl)-1,3-dioxolanes: New Diastereoisomeric Pure β-Acylvinyl Anion Equivalents

The reaction of (E)-chloroketals 1 with lithium powder and a catalytic amount of DTBB (4 mol percent) in THF at -90 deg C followed by treatment with different electrophiles tCHO, PhCHO, Me2CO, (CH2)4CO, PhCOMe> at -90 to -60 deg C