16136-84-8

Basic information

• Product Name: CIS-1-CHLOROPROPENE
• Synonyms: (z)-1-propen;1-chloro-(z)-propen;cis-1-chloro-prop-1-ene;Propene, 1-chloro-, (Z)-;propene,1-chloro-,(Z)-;1-CHLOROPROPENE;CIS-1-CHLORO-1-PROPENE;CIS-1-CHLOROPROPENE
• CAS NO: 16136-84-8
• Molecular Formula: C₃H₅Cl
• Molecular Weight: 76.52
• Mol File: 16136-84-8.mol
• Article Data: 13

Chemical Properties

• Melting Point: -134.8°C
• Boiling Point: 32.45°C
• Appearance: /
• Density: 0.9271
• Vapor Pressure: 486mmHg at 25°C
• Refractive Index: 1.4000
• CAS DataBase Reference: CIS-1-CHLOROPROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: CIS-1-CHLOROPROPENE(16136-84-8)
• EPA Substance Registry System: CIS-1-CHLOROPROPENE(16136-84-8)

Safety Data

• Hazardous Substances Data: 16136-84-8(Hazardous Substances Data)

Usage

General Description

CIS-1-CHLOROPROPENE, also known as chloropropene or allyl chloride, is a colorless and flammable liquid chemical compound. It is used primarily as a raw material in the production of various synthetic chemicals, including epichlorohydrin, which is used in the production of epoxy resins, and allyl alcohol, which is used in the production of plastics, pharmaceuticals, and other chemicals. It is also used as a pesticide, fumigant, and herbicide in agriculture. CIS-1-CHLOROPROPENE is known to be toxic and harmful if inhaled, ingested, or in contact with the skin or eyes, and it is important to handle it with caution and use proper protective equipment and procedures when working with this chemical.

InChI:InChI=1/C3H5Cl/c1-2-3-4/h2-3H,1H3/b3-2-

Upstream product

• 123-75-1 pyrrolidine 
• 26198-63-0 1,2-Dichloropropane 
• 110-91-8 morpholine 
• 109-89-7 diethylamine 
• 109-73-9 N-butylamine 
• 107-21-1 ethylene glycol 
• 187737-37-7 propene 
• 7782-50-5 chlorine 
• 13674-84-5 tris-(2-chloro, 1-methylethyl)-phosphate 
• 111-92-2 dibutylamine 
• 110-89-4 piperidine 
• 563-57-5 3,3-dichloropropene 
• 10061-02-6 (E)-1,3-dichloro-prop-1-ene 
• 10061-01-5 cis-1,3-Dichloropropene 

Downstream Products

• 78227-48-2 cis-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene 
• 503-17-3 dimethylacetylene 
• 3017-95-6 2-bromo-1-chloropropane 
• 80-62-6 methacrylic acid methyl ester 
• 107167-08-8 1-bromo-1-chloropropane 
• 32595-09-8 (1RS:2SR)-1,2-dibromo-1-chloro-propane 

Relevant articles and documents

Rates for 1,2 Migration in Alkylchlorocarbenes

-

Degradation of tri(2-chloroisopropyl) phosphate by the UV/H2O2 system: Kinetics, mechanisms and toxicity evaluation

A photodegradation technology based on the combination of ultraviolet radiation with H2O2 (UV/H2O2) for degrading tri(chloroisopropyl) phosphate (TCPP) was developed. In ultrapure water, a pseudo-first order reaction was observed, and the degradation rate constant reached 0.0035 min?1 (R2 = 0.9871) for 5 mg L?1 TCPP using 250 W UV light irradiation with 50 mg L?1 H2O2. In detail, the yield rates of Cl? and PO43? reached 0.19 mg L?1 and 0.58 mg L?1, respectively. The total organic carbon (TOC) removal rate was 43.02%. The pH value of the TCPP solution after the reaction was 3.46. The mass spectrometric detection data showed a partial transformation of TCPP into a series of hydroxylated and dechlorinated products. Based on the luminescent bacteria experimental data, the toxicity of TCPP products increased obviously as the reaction proceeded. In conclusion, degradation of high concentration TCPP in UV/H2O2 systems may result in more toxic substances, but its potential application for real wastewater is promising in the future after appropriate optimization, domestication and evaluation.

PROCESS FOR THE PRODUCTION OF CHLORINATED PROPANES AND/OR PROPENES

Processes for the production of chlorinated propenes are provided wherein the feedstream comprises 1,2-dichlropropane. The present processes make use of at least one reactor twice, i.e., at least two reactions occur in the same reactor. Cost and time savings are thus provided. Additional savings can be achieved by conducting more than two chlorination reactions, or all chlorination reactions, in one chlorination reactor, and/or by conducting more than two dehydrochlorination reactions, or all dehydrochlorination reactions, within a single dehydrochlorination reactor.