161432-01-5Relevant articles and documents
The solid-phase reaction of [60]fullerene: Novel addition of organozinc reagents
Wang, Guan-Wu,Murata, Yasujiro,Komatsu, Koichi,Wan, Terence S. M.
, p. 2059 - 2060 (1996)
Reaction of ethyl bromoacetate and zinc with [60]fullerene in the absence of any solvent, followed by quenching with acid affords 1-ethoxycarbonylmethyl-1,2- dihydro-[60]fullerene along with other minor byproducts including 1,4-bis(ethoxycarbonylmethyl)-1,4-dihydro[60]fullerene; a detailed reaction mechanism is proposed.