Chemical Communications p. 2059 - 2060 (1996)
Update date:2022-08-02
Topics:
Wang, Guan-Wu
Murata, Yasujiro
Komatsu, Koichi
Wan, Terence S. M.
Reaction of ethyl bromoacetate and zinc with [60]fullerene in the absence of any solvent, followed by quenching with acid affords 1-ethoxycarbonylmethyl-1,2- dihydro-[60]fullerene along with other minor byproducts including 1,4-bis(ethoxycarbonylmethyl)-1,4-dihydro[60]fullerene; a detailed reaction mechanism is proposed.
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