16205-14-4

Basic information

• Product Name: 2-methyl-3-phenyl-2H-azirene
• Synonyms: 2H-Azirine, 2-methyl-3-phenyl-
• CAS NO: 16205-14-4
• Molecular Formula: C₉H₉N
• Molecular Weight: 131.1745
• Mol File: 16205-14-4.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 199°C at 760 mmHg
• Flash Point: 65.5°C
• Density: 1.05g/cm³
• Vapor Pressure: 0.493mmHg at 25°C
• Refractive Index: 1.588
• CAS DataBase Reference: 2-methyl-3-phenyl-2H-azirene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-3-phenyl-2H-azirene(16205-14-4)
• EPA Substance Registry System: 2-methyl-3-phenyl-2H-azirene(16205-14-4)

Safety Data

• Hazardous Substances Data: 16205-14-4(Hazardous Substances Data)

Upstream product

• 637-50-3 1-phenylpropene 
• 93-55-0 1-phenyl-propan-1-one 
• 2157-50-8 propiophenone oxime 
• 873-66-5 1-propenylbenzene 
• 1532565-46-0 (1-azido-2-iodopropyl)benzene 

Downstream Products

• 1384520-12-0 1-(2-(4-methoxyphenyl)-5-methyl-4-phenyl-1H-pyrrol-3-yl)pyridinium bromide 
• 1431934-86-9 ethyl 2,6-dimethyl-3-phenyl-2H-1,4-oxazine-5-carboxylate 
• 485319-54-8 exo-2,6-dimethyl-4,5-diphenyl-1,3-diazabicyclo[3.1.0]hex-3-ene 
• 485319-54-8 endo-2,6-dimethyl-4,5-diphenyl-1,3-diazabicyclo-[3.1.0]hex-3-ene 
• 81793-18-2 N-ethylidenenebenzamide 
• 54600-85-0 2,5-dimethyl-3,6-diphenylpyrazine 
• 21120-36-5 1-fluoroethyl phenyl ketone 
• 39038-72-7 2,2-Difluoro-2-phenyl-1-methylethylamine 
• 86756-09-4 (1R,3R,4S,5S,6R)-3,6-Dimethyl-1,4,5-triphenyl-9-oxa-2,7-diaza-tricyclo[3.3.1.0^2,4]nonan-8-one 
• 61686-91-7 methyl-3 allyl-2 phenyl-2 aziridine 

Relevant articles and documents

Aziridation of Vinylsilanes and Vinylstannanes: A New Synthesis of Azirines

Aziridination of vinylsilanes and vinylstannanes with N-acetoxyaminoquinazolone (8) gave aziridines (1)-(7): caesium fluoride in dimethylformamide brought about elimination of trimethylsilyl and quinazolone groups from (1) and (2) to give the correspondin

A Domino Approach for the Synthesis of 4-Carboxamide Oxazolines from Azirines

A regio- and diastereoselective ring-expansion reaction of N-acylaziridines is described for the synthesis of 4-carboxamide oxazolines using InCl3. A domino Ugi-Joullié/ring-expansion reaction of arylphenylazirines, isocyanides, and carboxylic

General Synthesis of Tri-Carbo-Substituted N2-Aryl-1,2,3-triazoles via Cu-Catalyzed Annulation of Azirines with Aryldiazonium Salts

The general synthesis of fully substituted N2-aryl-1,2,3-triazoles is hitherto challenging compared with that of the N1-aryl counterparts. Herein, we describe a Cu-catalyzed annulation reaction of azirines and aryldiazonium salts. This regiospecific metho