1620511-33-2Relevant academic research and scientific papers
Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy
Wilson, Eleanor A.,Vermeulen, Nicolaas A.,McGonigal, Paul R.,Avestro, Alyssa-Jennifer,Sarjeant, Amy A.,Stern, Charlotte L.,Stoddart, J. Fraser
, p. 9665 - 9668 (2014)
Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process. This journal is the Partner Organisations 2014.
