1623-51-4Relevant articles and documents
Pellacani,Tardella
, p. 2725 (1978)
BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines
Di Nicola,Arcadi,Rossi
supporting information, p. 9895 - 9898 (2016/12/07)
1-Butyl-3-methylimidazolium hydrogen carbonate (BMIm HCO3) was used as an ionic liquid with carboxylating properties able to convert, in the presence of an alkyl halide, amines into the corresponding carbamate esters. Moderate to good yields of
Synthesis of carbamates from diethoxycarbonyl hydrazine derivatives by E1cB eliminative cleavage of the N-N′-bond rather than reduction
Magnus, Philip,Garizi, Negar,Seibert, Kimberly A.,Ornholt, Alexandra
supporting information; experimental part, p. 5646 - 5648 (2010/02/28)
[Chemical Equation Presented] Treatment of diethoxycarbonyl hydrazine derivatives with methyl bromoacetate/Cs2CO3/MeCN at 50°C followed by heating to 80°C resulted in N-N′ bond cleavage to the corresponding carbamates.