366491-15-8

Basic information

• Product Name: 1-Butyl-3-methylimidazolium hydrogen car
• Synonyms: 1-Butyl-3-methylimidazolium hydrogen car;1-Butyl-3-methylimidazolium bicarbonate;1-Butyl-3-methylimidazolium hydrogen carbonate solution;3-Butyl-1-methylimidazolium bicarbonate
• CAS NO: 366491-15-8
• Molecular Formula: CHO₃*C₈H₁₅N₂
• Molecular Weight: 200.2349
• Mol File: 366491-15-8.mol
• Article Data: 13

Chemical Properties

• Flash Point: 57 °C
• Appearance: /
• CAS DataBase Reference: 1-Butyl-3-methylimidazolium hydrogen car(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butyl-3-methylimidazolium hydrogen car(366491-15-8)
• EPA Substance Registry System: 1-Butyl-3-methylimidazolium hydrogen car(366491-15-8)

Safety Data

• Hazard Codes: T
• Statements: 20/21/22-36/37/38-39/23/24/25-23/24/25
• Safety Statements: 26-36/37-45
• RIDADR: UN 1987 3/PG 3
• Hazardous Substances Data: 366491-15-8(Hazardous Substances Data)

Usage

General Description

1-Butyl-3-methylimidazolium hydrogen car, also known as BMIM-HC, is a type of room temperature ionic liquid (RTIL) that contains the hydrogen cation (H+) and the carboxylate anion (C2H6O2). It is a colorless, water-soluble liquid and has gained attention as a potential green solvent due to its low volatility and thermal stability. BMIM-HC has been used in various applications, including catalysis, electrochemistry, and organic synthesis. It has also shown promise as an alternative electrolyte for lithium-ion batteries and has the potential to replace volatile organic solvents in industrial processes, making it a versatile and environmentally friendly chemical.

InChI:InChI=1/C8H15N2.CH2O3/c1-3-4-5-10-7-6-9(2)8-10;2-1-4-3/h6-8H,3-5H2,1-2H3;1,3H/q+1;/p-1

Upstream product

• 124-38-9 carbon dioxide 
• 79917-90-1 1-butyl-3-methylimidazolium chloride 
• 1066-33-7 ammonium bicarbonate 
• 144-55-8 sodium hydrogencarbonate 
• 85100-77-2 1-n-butyl-3-methylimidazolim bromide 
• 463-79-6 carbonic-acid 
• 298-14-6 potassium hydrogencarbonate 
• 584-08-7 potassium carbonate 
• 497144-87-3 1-butyl-3-methylimidazolium formate 

Downstream Products

• 174501-65-6 1-butyl-3-methylimidazolium Tetrafluoroborate 
• 1289675-16-6 1-methyl-3-butylimidazolium ibuprofenate 
• 2621-78-5 ethyl N-benzylcarbamate 
• 854885-85-1 ethyl (1-cyclohexylethyl)carbamate 
• 1623-51-4 α-Phenethylcarbamidsaeureethylester 
• 59325-16-5 ethyl cyclohexyl(methyl)carbamate 
• 101-99-5 N-carboethoxyaniline 
• 2621-80-9 ethyl p-chlorophenylcarbamate 
• 7107-58-6 benzyl N-cyclohexylcarbamate 
• 89-86-1 4-hydroxysalicylic acid 

Relevant articles and documents

Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol at Room Temperature Using Imidazolium Hydrogen Carbonate Ionic Liquid as a Recyclable Catalyst and Dehydrant

The direct synthesis of dimethyl carbonate (DMC) from CO2 and CH3OH was achieved at room temperature with 74 % CH3OH conversion in the presence of an imidazolium hydrogen carbonate ionic liquid ([CnCmIm][HCO3]). Experimental and theoretical results reveal that [CnCmIm][HCO3] can transform quickly into a CO2 adduct, which serves as an effective catalyst and dehydrant. Its dehydration ability is reversible. The energy barrier of the rate-determining step for the DMC synthesis is only 21.7 kcal mol?1. The ionic liquid can be reused easily without a significant loss of its catalytic and dehydrating ability.

Preparation method of antibacterial veterinary medicine quinocetone

The invention provides a preparation method of quinocetone which is a national first class new veterinary medicine initiated internationally and has antibacterial, diarrhea-stopping and growth-promoting effects. The preparation method comprises the following steps: adding alkaline ionic liquid into a reactor, adding benzofurazan and benzylidene acetylacetone, stirring, conducting reaction at room temperature, and performing aftertreatment on the reaction liquid after the reaction to obtain the quinocetone. The method is short in process step, mild in reaction condition, short in reaction time, high in efficiency, high in product yield and high in product purity; meanwhile, the alkaline ionic liquid provided by the invention is in a liquid state at room temperature, has high dissolubility on the raw materials and can serve as a catalyst and a reaction solvent of a reaction system, so that environmental pollution caused by an organic solvent is avoided and large-scale production is facilitated.

BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines

1-Butyl-3-methylimidazolium hydrogen carbonate (BMIm HCO3) was used as an ionic liquid with carboxylating properties able to convert, in the presence of an alkyl halide, amines into the corresponding carbamate esters. Moderate to good yields of