162470-59-9

Upstream product

• 87202-38-8 decanoyl benzoyl methane 
• 74-88-4 methyl iodide 
• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 
• 112-13-0 n-decanoyl chloride 
• 93-89-0 benzoic acid ethyl ester 
• 112-12-9 methyl nonyl ketone 
• 93-55-0 1-phenyl-propan-1-one 

Relevant academic research and scientific papers

Mild and efficient pentafluorophenylammonium triflate (PFPAT)-catalyzed C-acylations of enol silyl ethers or ketene silyl (Thio)acetals with acid chlorides

A pentafluorophenylammonium triflate (PFPAT) catalyst (5 mol %) successfully promoted C-acylation of enol silyl ethers with acid chloride to produce various β-diketones (12 examples; 62-92% yield). Similarly, C-acylation of ketene silyl acetals or ketene

Enantioselective borohydride reduction catalyzed by optically active cobalt complexes

The highly enantioselective borohydride reduction of aromatic ketones or imines to the corresponding alcohols was developed in the presence of a catalytic amount of an optically active cobalt(II) complex catalyst. This enantioselective reduction is carried out using a precisely premodified borohydride with alcohols such as tetrahydrofurfuryl alcohol, ethanol and methanol. High optical yields are obtained by choosing the appropriate alcohol as modifiers and a suitable β-ketoiminato ligand of the catalyst. The enantioselective borohydride reduction has been successfully applied to the preparation of optically active 1,3-diols, the stereoselective reduction of diacylferrocenes, and dynamic and/or kinetic resolution of 1,3-dicarbonyl compounds.