162777-19-7

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 59662-65-6 methylthiomethyl p-tolyl sulfone 

Downstream Products

• 4351-03-5 (E)-5-cyclohexylidene-2,4-pentadienal 
• 130649-72-8 (1E,3E)-1-(methylthio)-1-(p-tolylsulfonyl)-1,3-pentadiene 
• 132760-61-3 1-(methylthio)-5-(p-tolylsulfonyl)-1,3-pentadiene 
• 132760-60-2 5-(methylthio)-5-(p-tolylsulfonyl)-1,3-pentadiene 
• 132760-74-8 (E)-6-Phenyl-5-(toluene-4-sulfonyl)-hex-2-enal 
• 139452-82-7 1-Methyl-4-[1-((1E,3E)-4-methylsulfanyl-buta-1,3-dienyl)-cyclohexanesulfonyl]-benzene 
• 132760-62-4 1-(methylthio)-6-phenyl-5-(p-tolylsulfonyl)-1,3-hexadiene 
• 139452-84-9 1-Methyl-4-((3E,5E)-2-methyl-6-methylsulfanyl-1-phenyl-hexa-3,5-diene-2-sulfonyl)-benzene 
• 139452-81-6 1-((1E,3E)-5-Butyl-1-methylsulfanyl-nona-1,3-diene-5-sulfonyl)-4-methyl-benzene 
• 132760-63-5 1-(methylthio)-5-(p-tolylsulfonyl)-1,3-tetradecadiene 
• 139452-80-5 1-((3E,5E)-2-Benzyl-6-methylsulfanyl-1-phenyl-hexa-3,5-diene-2-sulfonyl)-4-methyl-benzene 
• 139452-86-1 1-Methyl-4-[9-((1E,3E)-4-methylsulfanyl-buta-1,3-dienyl)-heptadecane-9-sulfonyl]-benzene 
• 93039-33-9 1,2-diphenyl-3-<<(4-methylphenyl)sulfonyl>(methylthio)methylene>cyclopropene 
• 93039-34-0 [(2-Methoxy-1,3-diphenyl-cycloprop-2-enyl)-methylsulfanyl-(toluene-4-sulfonyl)-methyl]-trimethyl-silane 

Relevant academic research and scientific papers

A New and Convenient Preparation of Conjugated Dienals

For preparation of 5-monosubstituted or 5,5-disubstituted 2,4-dienals, 1-(methylthio)-5-(p-tolylsulfonyl)-1,3-pentadiene (4) is revealed to be an important precursor.When 5-(methylthio)-5-(p-tolylsulfonyl)-1,3-pentadiene, that is easily obtainable from (methylthio)methyl p-tolyl sulfone, was treated with silica gel, 1,5-rearrangement of p-tolylsulfonyl group occurred to give 4.The conditions for mono- or dialkylation of 4 followed by hydrolysis leading to the dienals are desribed.

Application of the Peterson Olefination to the Preparation of Substituted Triafulvenes from Methoxycyclopropenylium Triflates

Three new unusually substituted triafulvenes were prepared by reacting methoxycyclopropenylium triflates with α-silyl substituted anions.The mode of a nucleophilic attack varied, depending on the anion.Attack occurred at the methoxy substituted carbon, yi