16281-93-9

Basic information

• Product Name: dimethyl 2-(bromomethyl)-1,3-benzenedicarboxylate
• Synonyms: dimethyl 2-(bromomethyl)-1,3-benzenedicarboxylate
• CAS NO: 16281-93-9
• Molecular Weight: 287.11
• Mol File: 16281-93-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: dimethyl 2-(bromomethyl)-1,3-benzenedicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-(bromomethyl)-1,3-benzenedicarboxylate(16281-93-9)
• EPA Substance Registry System: dimethyl 2-(bromomethyl)-1,3-benzenedicarboxylate(16281-93-9)

Safety Data

• Hazardous Substances Data: 16281-93-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 3537-62-0 2-methyl-1,3-benzenedicarbonyl dichloride 
• 28269-31-0 dimethyl 2-methylbenzene-1,3-dicarboxylate 
• 626-17-5 benzene-1,3-dicarbonitrile 
• 2317-22-8 2,6-dicyanotoluene 
• 15120-47-5 2-methyl-1,3-benzenedicarbocylic acid 
• 118-69-4 2,6-dichlorotoluene 

Downstream Products

• 131980-49-9 dimethyl 2-methoxymethylbenzene-1,3-dicarboxylate 
• 131079-21-5 C₂₄H₂₆O₁₀ 
• 4792-27-2 1,3-dihydro-1-oxo-4-isobenzofurancarboxylic acid 
• 91344-99-9 methyl 1,3-dihydro-1-oxo-4-isobenzofuranacetate 
• 131980-48-8 2-methoxymethylbenzene-1,3-dimethanol 
• 131980-50-2 1,3-bis(bromomethyl)-2-methoxymethylbenzene 
• 131079-23-7 C₂₀H₂₂Br₄O₂ 
• 131079-22-6 {2-[2-(2,6-Bis-hydroxymethyl-benzyloxy)-ethoxymethyl]-3-hydroxymethyl-phenyl}-methanol 

Relevant articles and documents

Design and synthesis of a trifunctional chiral porphyrin with C2 symmetry as a chiral recognition host for amino acid esters

An intrinsic chiral recognition host, (R,R)- or (S.S)-[trans-5,15-bis(2-hydroxyphenyl)-10-{2,6-bis((methoxycarbonyl)m ethyl)phenyl}-2,3,17,18-tetraethylporphyrinato]zinc(II) (1), was synthesized by the coupling between (3,3',4,4'-tetraethyl-5,5'-bis(α-hyd

Synthesis of 9-Methoxymethyl-18-methyl-2,11-dithiametacyclophane: a Dithiametacyclophane with a Protected Internal Benzylic Functional Group

A synthetic route to a dithiametacyclophane with a benzylic functional (methoxymethyl) group at C9 is described.The benzylic function however had to be introduced at a later stage in the synthetic scheme to optimize the overall yield.Only the anti isomer of the desired dithiacyclophane (7) was isolated.The entire methoxymethyl group lies within the shielding zone of the opposite benzene ring as indicated in the 1H n.m.r. spectrum.Attempts to convert anti-(7) into the novel aromatic system (5b) by a rearrangement-elimination sequence however failed.