1629168-06-4Relevant academic research and scientific papers
Total synthesis of (2RS)-α-tocopherol through Ni-catalyzed 1,4-addition to a chromenone intermediate
Termath, Andreas Ole,Velder, Janna,Stemmler, Rene T.,Netscher, Thomas,Bonrath, Werner,Schmalz, Hans-Guenther
, p. 3337 - 3340 (2014/06/09)
A novel strategy for the total synthesis of α-tocopherol ("vitamin E") was elaborated on the basis of the conjugate addition of AlMe3 (as a methyl anion equivalent) to a 2-substituted chromenone. Starting from trimethylhydroquinone and (R,R)-he
