16372-96-6Relevant articles and documents
CuI in biorenewable basic medium: Three novel and low E-factor Suzuki-Miyaura cross-coupling reactions
Lakshmidevi, Jangam,Naidu, Bandameeda Ramesh,Venkateswarlu, Katta
, (2022/03/31)
In this article, we have disclosed three inexpensive and novel copper-catalyzed C(sp2)–C(sp2) coupling reactions of substituted aryl/heteroaryl halides with arylboronic acids by employing water extract of pomegranate ash (WEPA) as biorenewable base and aqueous reaction medium. CuI/WEPA, CuI/WEPA/DABCO, CuI/WEPA/SPhos catalytic systems were developed for the present Suzuki-Miyaura coupling. WEPA has been found to be the effective base and reaction medium for copper-catalysed Suzuki-Miyaura reactions with and without ligands to provide good to high yields of coupling products. This method has remarkable advantages like inexpensive and waste-derived biorenewable base, low catalyst loading, moderate temperature, replacement of precious palladium with abundant copper, no or negligible contamination of copper in products, low E-factor, high chemoselectivity and a large substrate scope.
Organic compound, and organic electroluminescent device and electronic device using same
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Paragraph 0157-0159, (2021/02/20)
The invention relates to an organic compound. The structure of the organic compound comprises a formula I. When the organic compound provided by the invention is used for a light-emitting layer of anorganic electroluminescent device, the device efficiency of the device can be effectively improved, and the service life of the organic electroluminescent device is prolonged.
Phosphorescent OLED and hole transporting materials for phosphorescent OLEDS
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Page/Page column 13, (2020/12/23)
The present invention relates to phosphorescent organic light-emitting diodes (OLEDs) including a hole-transporting or a hole-transporting and an electron-blocking layer including an N,N,N′,N′-tetraaryl-phenylene-3,5-diamine or an N,N,N′,N′-tetraaryl-1,1′-biphenyl-3,3′-diamine matrix compound and to new N,N,N′,N′-tetraarylsubstituted m-arylene diamine compounds useful as hole-transporting and electron-blocking layer matrices in phosphorescent OLEDs.