163772-78-9Relevant academic research and scientific papers
Intramolecular Anti-Carbolithiation of Alkynes: Stereo-Directing Effect of Lithium-Coordinating Substituents
Ly, Kim Uyen,Boussonnière, Anne,Castanet, Anne-Sophie
, (2022/01/19)
This paper presents the results of our investigations on the stereochemical course of intramolecular carbolithiation of alkynes. It is shown that the presence of a lithium-chelating propargylic substituent completely reverses the otherwise favored syn-pro
5-endo-Trigonal Radical Cyclisation - a General Procedure for Making Five-Membered Rings
Clive, Derrick L. J.,Cantin, Michel
, p. 319 - 320 (2007/10/02)
Silicon-centred radicals, derived from alkoxy dialkyl silanes by intramolecular hydrogen transfer, undergo 5-endo-trigonal closure.
