96557-30-1

Basic information

• Product Name: 2-(2-BROMOPHENYL)ACETALDEHYDE
• Synonyms: 2-(2-BROMOPHENYL)ACETALDEHYDE;2-bromophenylacetaldehyde;1-BroMo-2-(forMylMethyl)benzene;2-BroMobenzeneacetaldehyde;Benzeneacetaldehyde, 2-bromo-
• CAS NO: 96557-30-1
• Molecular Formula: C₈H₇BrO
• Molecular Weight: 199.04458
• Product Categories: Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 96557-30-1.mol
• Article Data: 38

Chemical Properties

• Boiling Point: 262.1 °C at 760 mmHg
• Flash Point: 95.8 °C
• Appearance: /
• Density: 1.466 g/cm³
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• Solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 2-(2-BROMOPHENYL)ACETALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-BROMOPHENYL)ACETALDEHYDE(96557-30-1)
• EPA Substance Registry System: 2-(2-BROMOPHENYL)ACETALDEHYDE(96557-30-1)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Hazardous Substances Data: 96557-30-1(Hazardous Substances Data)

Usage

Uses

(2-Bromophenyl)acetaldehyde is a di-substituted benzene used in the preparation of various compounds such as phenanthrenes.

Upstream product

• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 6630-33-7 ortho-bromobenzaldehyde 
• 2142-69-0 2-bromophenyl methyl ketone 
• 2039-88-5 2-bromostyrene 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 109-92-2 ethyl vinyl ether 
• 615-36-1 2-bromoaniline 
• 130089-21-3 Methyl-3-(2-bromphenyl)-2-oxirancarboxylat 
• 107408-16-2 3-(o-bromophenyl)propanal 
• 583-55-1 1-Bromo-2-iodobenzene 
• 57486-69-8 methyl 2-(2-bromophenyl)acetate 
• 130089-23-5 trans-1-Brom-2-(2-methoxyvinyl)-benzol 
• 87-91-2 diethyl (2R,3R)-tartrate 
• 112396-13-1 2-(2-bromophenyl)acetaldehyde dimethyl acetal 

Downstream Products

• 452055-99-1 ethyl (E)-4-(2-bromophenyl)-2-butenoate 
• 934355-54-1 C₂₀H₂₂BrNO₄ 
• 839673-82-4 1-(2'-bromobenzyl)-N-tert-butyloxycarbonyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 
• 405938-59-2 6-(2-bromo-phenyl)-4-methyl-hex-4-enoic acid ethyl ester 
• 729572-37-6 1-(2-bromobenzyl)-2-p-toluenesulfonamide-1,2,3,4-tetrahydroisoquinolin-7-ol 
• 335165-04-3 rac-1-(2-bromophenyl)-4-(trimethylsilyl)but-3-yn-2-ol 
• 405938-56-9 1-(2-bromo-phenyl)-3-methyl-but-3-en-2-ol 

Relevant articles and documents

Intramolecular Anti-Carbolithiation of Alkynes: Stereo-Directing Effect of Lithium-Coordinating Substituents

This paper presents the results of our investigations on the stereochemical course of intramolecular carbolithiation of alkynes. It is shown that the presence of a lithium-chelating propargylic substituent completely reverses the otherwise favored syn-pro

Peroxygenase-Catalysed Epoxidation of Styrene Derivatives in Neat Reaction Media

Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.

Stereoselective synthesis of 3,4-di-substituted mercaptolactones via photoredox-catalyzed radical addition of thiophenols

A visible light mediated radical addition of thiophenols on 4-phenylbut-3-enoic acids to give diastereoselective synthesis of 3,4-disubstituted γ-lactones is reported. The reaction precludes the conventional prerequisite of conjugate addition. Furthermore, the lactones were successfully utilized in the synthesis of γ-ketoamides.