163776-50-9Relevant academic research and scientific papers
Asymmetric approaches to 1,2-disubstituted mitosenes based on the intramolecular cyclization of diazoesters
Lee, Sangku,Lim, Hee-Jong,Cha, Kobpurn Lulu,Sulikowski, Gary A.
, p. 16521 - 16532 (2007/10/03)
A strategy for the asymmetric synthesis of 1,2-disubstituted mitosenes is described. The key reaction is the decomposition of a meso diazoester in the presence of chiral copper(I) catalysts. Cyclization of diazoesters derived from (1R, 2S, 5R)-menthol and
