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16414-81-6

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16414-81-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 16414-81-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,4,1 and 4 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 16414-81:
(7*1)+(6*6)+(5*4)+(4*1)+(3*4)+(2*8)+(1*1)=96
96 % 10 = 6
So 16414-81-6 is a valid CAS Registry Number.

16414-81-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (2,4-dimethylphenoxy)-trimethylsilane

1.2 Other means of identification

Product number -
Other names 2,4-Dimethylphenoxytrimethylsilane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16414-81-6 SDS

16414-81-6Relevant articles and documents

Differentiation of isomeric cresols by silylation in combination with gas chromatography/mass spectrometry analysis

Xu, Jiaxiang,Zhu, Guohua,Zhang, Huarong,Liu, Jinsong,Jiang, Kezhi

, (2020/01/21)

Rationale: m-Cresol is listed as a priority controlled contaminant in many countries, but it is very difficult to accurately determine isomeric cresols due to their incomplete chromatographic separation on commercially available chromatographic columns and their nearly identical mass spectra. Methods: Silylation of isomeric cresols was carried out by treatment with N-methyl-N-(trimethylsilyl)trifluoroacetamide. The formed trimethyl(tolyloxy)silanes were analyzed by gas chromatography/mass spectrometry (GC/MS). Theoretical calculations were carried out with the Gaussian 03 program using the density functional theory (DFT) method at the B3LYP/6-311 + G(2d,p) level. Results: The derivatives of three isomeric cresols and six isomeric xylenols have been completely separated on an HP-5MS capillary column within a GC run of only 10 minutes. In addition, the derivative o-cresol can be very easily differentiated from its isomers due to its characteristic base peak ion at m/z 91 in electron ionization (EI)-MS. DFT calculation results indicated that the formation of the abundant fragment ion at m/z 91 is attributed to a facile dissociation pathway involving the shift of a neighboring phenylmethyl hydrogen atom in EI-MS of trimethyl(o-tolyloxy)silane. Conclusions: Silylation provides a promising solution for simultaneous determination of isomeric cresols and isomeric xylenols.

Regioselectivity of Hydroxyl Radical Reactions with Arenes in Nonaqueous Solutions

Moores, Lee C.,Kaur, Devinder,Smith, Mathew D.,Poole, James S.

, p. 3260 - 3269 (2019/03/11)

The regioselectivity of hydroxyl radical addition to arenes was studied using a novel analytical method capable of trapping radicals formed after the first elementary step of reaction, without alteration of the product distributions by secondary oxidation processes. Product analyses of these reactions indicate a preference for o- over p-substitution for electron donating groups, with both favored over m-addition. The observed distributions are qualitatively similar to those observed for the addition of other carbon-centered radicals, although the magnitude of the regioselectivity observed is greater for hydroxyl. The data, reproduced by high accuracy CBS-QB3 computational methods, indicate that both polar and radical stabilization effects play a role in the observed regioselectivities. The application and potential limitations of the analytical method used are discussed.

Rice husk: Introduction of a green, cheap and reusable catalyst for the protection of alcohols, phenols, amines and thiols

Shirini, Farhad,Akbari-Dadamahaleh, Somayeh,Mohammad-Khah, Ali,Aliakbar, Ali-Reza

, p. 164 - 170 (2014/03/21)

A mild, efficient and eco-friendly protocol for the chemoselective protection of benzylic and primary and less hindered secondary aliphatic alcohols and phenols as trimethylsilyl ethers and different types of amines as N-tert-butylcarbamates is developed using rice husk (RiH) as the catalyst. This reagent is also able to catalyze the acetylation of alcohols, phenols, thiols and amines with acetic anhydride. Easy work-up, relatively short reaction times, excellent yields and low cost, availability and reusability of the catalyst are the striking features of this methodology, which can be considered to be one of the best and general methods for the protection of alcohols, phenols, thiols and amines. In addition, the use of a green reagent in the above-mentioned reactions results in a reduction of environmental pollution and of the cost of the applied methods.

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