164352-04-9Relevant academic research and scientific papers
Benzylation of arenes with benzyl ethers promoted by the in situ prepared superacid BF3-H2O
Li, Yu,Xiong, Yan,Li, Xueming,Ling, Xuege,Huang, Ruofeng,Zhang, Xiaohui,Yang, Jianchun
supporting information, p. 2976 - 2981 (2014/06/10)
An efficient and environmentally friendly benzylation of arenes with benzyl ethers as benzyl donors using BF3-Et2O to generate in situ the superacid BF3-H2O as an efficient promotor has been described. A wide variety of functional groups have been investigated and found to be compatible to give the desired diarylmethanes in yields of up to 99%. The crucial role of the moisture content in this transformation has been demonstrated by detailed investigations. This journal is the Partner Organisations 2014.
A novel, efficient, and highly selective O-Bn bond cleavage reaction via a rare K-induced electron transfer process
Shi, Lei,Wu, Jiong Xia,Fu, Min Zhang,Yong, Qiang Tu
, p. 1505 - 1507 (2007/10/03)
A new, efficient and highly selective deprotective method of both benzyl and benzylidene groups for protection of monohydroxyl and dihydroxyl, respectively, has been developed by using the system K-t-BuNH2-t-BuOH-18-crown-6. This method is valu
