164718-49-4

Basic information

• Product Name: Magnesium,2-Phenyl-1,3-Dioxolane,Bromide
• Synonyms: Magnesium,2-Phenyl-1,3-Dioxolane,Bromide;2-(1,3-Dioxolan-2-yl)phenylmagnesium bromide, 0.50 M in THF;2-(1,3-Dioxolan-2-yl)phenylmagnesium bromide 0.5 M in Tetrahydrofuran
• CAS NO: 164718-49-4
• Molecular Formula: C₉H₉BrMgO₂
• Molecular Weight: 256.39938
• Mol File: 164718-49-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Magnesium,2-Phenyl-1,3-Dioxolane,Bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Magnesium,2-Phenyl-1,3-Dioxolane,Bromide(164718-49-4)
• EPA Substance Registry System: Magnesium,2-Phenyl-1,3-Dioxolane,Bromide(164718-49-4)

Safety Data

• Hazardous Substances Data: 164718-49-4(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 34824-58-3 2-(2-bromophenyl)-1,3-dioxolan 

Downstream Products

• 185896-84-8 ethyl 2-(2-( 1,3-dioxolan-2-yl)phenyl)-2-oxoacetate 
• 941598-12-5 [HgBr(η2-C6H4-2-CH(O2C2H4))] 
• 1421840-47-2 (S)-4-chloro-2-[(1R)-1-{[(4-methylphenyl)sulfonyl]amino}ethyl]phenyl-2-(1,3-dioxolan-2-yl)phenyl(phenyl)phosphinate 
• 185896-85-9 (2-[1,3]dioxolan-2-yl-phenyl)-methoxyimino-acetic acid ethyl ester 
• 185896-83-7 (Z)-2-[2-(1,3-dioxolan-2-yl)phenyl]-2-methoxyimino-N-methylacetamide 
• 50777-76-9 (2-formylphenyl)(diphenyl)phosphine 
• 50777-73-6 2-(ortho-diphenylphosphinophenyl)-1,3-dioxolane 

Relevant articles and documents

o-diphenylphosphinobenzaldehyde complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structure

Preparation of the o-diphenylphosphinobenzaldehyde complexes of Pd(II) and Pt(II), with general formulae [MX2L2], [Pd 2Me2(μ-Cl)2L2] and [PdMeClL 2] where [M = Pd or Pt; X = Cl, Br, I and L = o- diphenylphosphinobenzaldehyde, {PPh2(o-C6H 4CHO)}], is reported here. All complexes have been characterized by elemental analysis, IR, NMR (1H, 13C, 31P and 195Pt) and UV-visible spectroscopy, that allowed the deduction of the stereochemistry for the complexes. The mononuclear complexes have been found to adopt the trans configuration in square-planar geometries. The molecular structure of trans-[PdCl2{PPh2(C6H 4CHO)}2] has been established by a single crystal X-ray diffraction study and confirms the spectroscopic conclusions.