16519-25-8

Basic information

• Product Name: (3-phenoxyprop-1-en-1-yl)benzene
• CAS NO: 16519-25-8
• Molecular Formula: C₁₅H₁₄O
• Molecular Weight: 210.2711
• Mol File: 16519-25-8.mol
• Article Data: 73

Chemical Properties

• Boiling Point: 354.5°C at 760 mmHg
• Flash Point: 141.3°C
• Density: 1.057g/cm³
• Vapor Pressure: 6.8E-05mmHg at 25°C
• Refractive Index: 1.604
• CAS DataBase Reference: (3-phenoxyprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (3-phenoxyprop-1-en-1-yl)benzene(16519-25-8)
• EPA Substance Registry System: (3-phenoxyprop-1-en-1-yl)benzene(16519-25-8)

Safety Data

• Hazardous Substances Data: 16519-25-8(Hazardous Substances Data)

Usage

General Description

"(3-phenoxyprop-1-en-1-yl)benzene" is a chemical compound with the molecular formula C18H18. It is composed of a benzene ring attached to a (3-phenoxyprop-1-en-1-yl) group. (3-phenoxyprop-1-en-1-yl)benzene is commonly used as a fragrance ingredient in various consumer products, including perfumes, colognes, and air fresheners. It is known for its sweet and floral scent, making it a popular choice for adding a pleasant aroma to a wide range of products. However, it is important to handle this chemical with care, as it can be irritating to the skin and eyes and may cause allergic reactions in some individuals.

Upstream product

• 86537-61-3 ethyl cinnamylcarbonate 
• 108-95-2 phenol 
• 85217-69-2 cinnamyl methyl carbonate 
• 2687-12-9 cinnamyl chloride 
• 127301-11-5 2-[(3-phenyl-2-propen-1-yl)oxy]benzoic acid 
• 119-36-8 methyl salicylate 
• 83611-87-4 methyl 2-[(3-phenyl-2-propen-1-yl)oxy]benzoate 
• 21040-45-9 Cinnamyl acetate 
• 138621-76-8 phenyl (E)-3-phenyl-2-propenyl carbonate 
• 109-72-8 n-butyllithium 
• 134478-80-1 1-bromo-2-[(3-phenylprop-2-enyl)oxy]benzene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 98-80-6 phenylboronic acid 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 

Downstream Products

• 108-95-2 phenol 
• 38276-75-4 2-(1-phenylallyl)phenol 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 1076-66-0 3-phenyl-1,5-hexadiene 
• 4439-45-6 1,6-diphenyl-hexa-1,5-diene 
• 56644-04-3 (E)-1-phenyl-1,5-hexadiene 
• 74120-63-1 (E)-1,4-diphenyl-1,5-hexadiene 
• 21148-30-1 3-(4-hydroxyphenyl)-1-phenylprop-1-ene 
• 133039-41-5 (E)-1-phenyl-3-(thiophen-3-yl)propene 
• 18916-11-5 (E)-1-methyl-2-(3-phenyl-2-propen-1-yl)benzene 
• 6948-68-1 (E)-1-chloro-4-(3-phenyl-2-propen-1-yl)benzene 
• 20442-73-3 (1E)-3-(4-methoxyphenyl)-1-phenylpropene 
• 5751-29-1 1-[(2E)-3-phenyl-2-propen-1-yl]naphthalene 
• 1374004-36-0 methyl (E)-2-(2,5-dimethyl-1-phenyl-1H-pyrrole-3-carbonyl)-5-phenylpent-4-enoate 

Relevant articles and documents

Synthesis of Enantioenriched 3,4-Disubstituted Chromans through Lewis Base Catalyzed Carbosulfenylation

A method for the catalytic, enantioselective, carbosulfenylation of alkenes to construct 3,4-disubstituted chromans is described. Alkene activation proceeds through the intermediacy of enantioenriched, configurationally stable thiiranium ions generated from catalytic, Lewis base activation of an electrophilic sulfenylating agent. The transformation affords difficult-to-generate, enantioenriched, 3,4-disubstituted chromans in moderate to high yields and excellent enantioselectivities. A variety of substituents are compatible including electronically diverse functional groups as well as several functional handles such as aryl halides, esters, anilines, and phenols. The resulting thioether moiety is amenable to a number of functional group manipulations and transformations. Notably, the pendant sulfide was successfully cleaved to furnish a free thiol which readily provides access to most sulfur-containing functional groups which are present in natural products and pharmaceuticals.

Covalent Organic Framework as a Heterogeneous Ligand for the Regioselective Oxidative Heck Reaction

A simple imine-based covalent organic framework (COF) as heterogeneous ligand for PdII-promoted Heck reaction is reported. Good regioselectivity for a wide range of electronically unbiased olefins is obtained (linear/branched >100:1 in most cases). Related tests and density functional theory calculations are used to explore the reason underlying the high selectivity. This research opens a route for COF as an intriguing platform to control regioselectivity catalysis.

Vinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation

Vinyl sulfonium salts typically act as an electrophilic Michael acceptor, thus initiating many tandem cyclization reactions. Herein, we disclosed the novel reactivity of vinyl sulfonium salts as a radical acceptor. Using redox-active ester as an alkyl rad