165269-52-3Relevant academic research and scientific papers
A Homoleptic Arylmanganese(II) Complex: Synthesis and Structure of a Thermally Stable Trinuclear Mesitylmanganese(II) Complex
Gambarotta, Sandro,Floriani, Carlo,Chiesi-Villa, Angiola,Guastini, Carlo
, p. 1128 - 1129 (1983)
The reaction of MnCl2 with mesMgBr (mes = 2,4,6-C6H2Me3) gave crystals of the linear trimer mes6Mn3 with bridging mesityl groups and the two end Mn atoms three-co-ordinated with a terminal mesityl; the Mn-C bond distances range from 2.10(1) to 2.35(1) Angstroem and the Mn ...Mn distance is 2.851(3) Angstroem.
Cationic arylmanganese(II) derivatives occurring in ion-pair forms with tetraphenylborate anions: Synthetic, structural, and magnetic studies
Solari, Euro,Musso, Fabrizio,Gallo, Emma,Floriani, Carlo,Re, Nazzareno,Chiesi-Villa, Angiola,Rizzoli, Corrado
, p. 2265 - 2276 (2008/10/09)
We report a class of cationic manganese(II) aryl compounds stabilized by weak donor solvents or by interactions with the counteranion BPh4- to form ion-pair species. The parent compound used was Mn3Mes6 (1; Mes
