A Homoleptic Arylmanganese(II) Complex: Synthesis and Structure of a Thermally Stable Trinuclear Mesitylmanganese(II) Complex

DOI: 10.1039/c39830001128

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1128 - 1129 (1983)

Update date:2022-08-03

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Authors:

Gambarotta, Sandro

Floriani, Carlo

Chiesi-Villa, Angiola

Guastini, Carlo

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Article abstract of DOI:10.1039/c39830001128

The reaction of MnCl2 with mesMgBr (mes = 2,4,6-C6H2Me3) gave crystals of the linear trimer mes6Mn3 with bridging mesityl groups and the two end Mn atoms three-co-ordinated with a terminal mesityl; the Mn-C bond distances range from 2.10(1) to 2.35(1) Angstroem and the Mn ...Mn distance is 2.851(3) Angstroem.

Full text of DOI:10.1039/c39830001128

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