A Homoleptic Arylmanganese(II) Complex: Synthesis and Structure of a Thermally Stable Trinuclear Mesitylmanganese(II) Complex

DOI: 10.1039/c39830001128

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1128 - 1129 (1983)

Update date:2022-08-03

Topics:

Authors:

Gambarotta, Sandro

Floriani, Carlo

Chiesi-Villa, Angiola

Guastini, Carlo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001128

The reaction of MnCl2 with mesMgBr (mes = 2,4,6-C6H2Me3) gave crystals of the linear trimer mes6Mn3 with bridging mesityl groups and the two end Mn atoms three-co-ordinated with a terminal mesityl; the Mn-C bond distances range from 2.10(1) to 2.35(1) Angstroem and the Mn ...Mn distance is 2.851(3) Angstroem.

Full text of DOI:10.1039/c39830001128

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mn₃(2,4,6-C₆H₂Me₃)6*toluene

Cas No:165269-52-3

R&D Labs maybe for 165269-52-3

Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158

Relevant to this article

Catalytic asymmetric synthesis of dihydrofurans and cyclopentenols with tertiary stereocenters

Doi:10.1002/ejoc.201301476
(2014)
One-pot isocyanide-based five-component reaction: Synthesis of highly functionalized N-cyclohexyl-2-(2,4-dioxo-2,3,4,5 tetrahydro-1H-benzo[b][1,5]diazepin-3-yl)-2-phenylacetamides

Doi:10.1080/00397911.2016.1271894
(2017)
Isolation of a stable, acyclic, two-coordinate silylene

Doi:10.1021/ja301091v
(2012)
An efficient one-pot synthesis of substituted 1h-naphtho[2,1-b]pyrans and 4h-1-benzopyrans (=Chromenes) under solvent-free microwave-irradiation conditions

Doi:10.1002/hlca.201100332
(2012)
An asymmetric iodolactonization reaction catalyzed by a zinc bis-proline-phenol complex

Doi:10.1016/j.tetlet.2013.11.028
(2014)
Diastereoselectivity in the intramolecular cycloaddition reactions of nitrones derived from 5-alkenals and chiral hydroxylamines

Doi:10.1016/0040-4039(91)80004-P
(1991)

Article Doi