1653-33-4

Basic information

• Product Name: 4-TETRADECANOL
• Synonyms: 4-TETRADECANOL;tetradecan-4-ol
• CAS NO: 1653-33-4
• Molecular Formula: C₁₄H₃₀O
• Molecular Weight: 214.39
• EINECS: 216-724-7
• Mol File: 1653-33-4.mol
• Article Data: 3

Chemical Properties

• Melting Point: 24 °C
• Boiling Point: 284.54°C (estimate)
• Flash Point: 110.4°C
• Appearance: /
• Density: 0.8097 (estimate)
• Vapor Pressure: 0.000628mmHg at 25°C
• Refractive Index: 1.4237 (estimate)
• PKA: 15.27±0.20(Predicted)
• CAS DataBase Reference: 4-TETRADECANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-TETRADECANOL(1653-33-4)
• EPA Substance Registry System: 4-TETRADECANOL(1653-33-4)

Safety Data

• Hazardous Substances Data: 1653-33-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H30O/c1-3-5-6-7-8-9-10-11-13-14(15)12-4-2/h14-15H,3-13H2,1-2H3

Upstream product

• 112-44-7 undecylaldehyde 
• 927-77-5 n-propylmagnesium bromide 
• 26496-20-8 tetradecan-4-one 
• 41884-32-6 (E)-2-tetradecen-4-ol 
• 699008-01-0 1,3-Dimethyl-2-[((E)-1-propenyl)-undecyloxymethyl]-benzene 
• 123-72-8 butyraldehyde 
• 629-59-4 tetradecane 
• 17049-50-2 n-decyl magnesium bromide 

Relevant articles and documents

Scope and limitations of lithium-ethylenediamine-THF-mediated cleavage at the α-position of aromatics: Deprotection of aryl methyl ethers and benzyl ethers under mild conditions

The scope and limitation of lithium-ethylenediamine-THF-mediated reductive bond cleavage at the α-position of aromatics were examined. Very mild conditions such as lithium metal (5 equiv) and ethylenediamine (7 equiv) in oxygen-free THF were quite effective for the demethylation of aromatic ethers even at as low as -10°C. Allyl benzyl ethers were also deprotected under these conditions with very little change of the allylic alcohol moiety. Through this study, 2,6-dimethylbenzyl (m-xylylmethyl, MXM) group was developed as an alternative of benzyl group, which is readily cleavable under the above mentioned reductive conditions.

Shape-selective Alkane Hydroxylation

A series of sterically hindered manganese porphyrins have been used to catalyse shape-selective alkane hydroxylation, increasing the production of primary alcohols.