16651-47-1

Usage

Uses

Used in Chemical Synthesis:
ACETIC-13C2 ACID is used as a reagent for chemical synthesis, particularly in the production of 13C labeled compounds. The use of 13C labeled compounds allows for the tracking and analysis of chemical reactions and metabolic pathways.
Used in Pharmaceutical Industry:
ACETIC-13C2 ACID is used as a reagent in the synthesis of 13C labeled pharmaceutical compounds. This allows for the study of drug metabolism and pharmacokinetics, as well as the development of new drugs with improved properties.
Used in Environmental Studies:
ACETIC-13C2 ACID is used as a tracer in environmental studies to track the movement and fate of acetic acid in various ecosystems. This helps in understanding the role of acetic acid in environmental processes and its impact on the environment.
Used in Analytical Chemistry:
ACETIC-13C2 ACID is used as an internal standard in analytical chemistry for the quantification and identification of compounds. The use of 13C labeled internal standards improves the accuracy and precision of analytical measurements.
Used in Educational Purposes:
ACETIC-13C2 ACID is used as a teaching aid in educational settings to demonstrate the principles of isotope labeling and its applications in various fields. This helps students understand the importance of isotope labeling in scientific research and its practical applications.

InChI:InChI=1/C2H4O2/c1-2(3)4/h1H3,(H,3,4)/i1+1,2+1

Upstream product

• 1632-98-0 [1,2-13C₂]acetaldehyde 
• 35121-31-4 ⁽¹³⁾C₂-acetylene 
• 7732-18-5 water 
• 14742-26-8 [¹³C]methanol 
• 1641-69-6 [13C]Carbon monoxide 
• 6532-48-5 methane 
• 1111-72-4 carbon dioxide 

Downstream Products

• 286367-78-0 ¹³C-dichloroacetic acid 
• 1633-47-2 [¹³C₂]-chloroacetic acid 
• 52947-00-9 bromo[1,2-¹³C₂]acetic acid 
• 61898-49-5 ethyl bromoacetate-⁽¹³⁾C₂ 
• 600726-26-9 [1,2-13C]acetamide 
• 113638-93-0 <1,2-13C2>Acetyl Bromide 

Relevant academic research and scientific papers

Identification of active surface species for friedel-crafts acylation and koch carbonylation reactions by insitu solid-state NMR spectroscopy

Finding the culprits: Insitu NMR spectroscopy combined with theoretical calculations show the formation of acetyl species covalently bound to framework oxygen atoms in acid zeolites. These species, and not the usually assumed acylium cations, are the reac

Ultrathin WO3·0.33H2O Nanotubes for CO2 Photoreduction to Acetate with High Selectivity

Artificial photosynthesis from CO2 reduction is severely hampered by the kinetically challenging multi-electron reaction process. Oxygen vacancies (Vo) with abundant localized electrons have great potential to overcome this limitation. However, surface Vo usually have low concentrations and are easily oxidized, causing them to lose their activities. For practical application of CO2 photoreduction, fabricating and enhancing the stability of Vo on semiconductors is indispensable. Here we report the first synthesis of ultrathin WO3·0.33H2O nanotubes with a large amount of exposed surface Vo sites, which can realize excellent and stable CO2 photoreduction to CH3COOH in pure water under solar light. The selectivity for acetum generation is up to 85%, with an average productivity of about 9.4 μmol g-1 h-1. More importantly, Vo in the catalyst are sustainable, and their concentration was not decreased even after 60 h of reaction. Quantum chemical calculations and in situ DRIFT studies revealed that the main reaction pathway might be CO2 → ?COOH → (COOH)2 → CH3COOH.

Hierarchically Porous Metal–Organic Framework/MoS2 Interface for Selective Photocatalytic Conversion of CO2 with H2O into CH3COOH

Metal–organic frameworks (MOFs) provide a platform to design new heterogeneous catalysts for catalytic CO2 reduction, but selective formation of C2 valuable liquid fuel products remains a challenge. Herein, we propose a strategy to synthesize composites by integrating MoS2 nanosheets into hierarchically porous defective UiO-66 (d-UiO-66) to form Mo-O-Zr bimetallic sites on the interfaces between UiO-66 and MoS2. The active interfaces are favorable for the efficient transfer of photo-generated charge carriers and for promoting the activity, whereas, the synergy of the components at the interfaces achieves selectivity for C2 production. The d-UiO-66/MoS2 composite facilitates the photo-catalytic conversion of gas phase CO2 and H2O to CH3COOH under visible light irradiation without any other adducts. The evolution rate and selectivity of CH3COOH reached 39.0 μmol g?1 h?1 and 94 %, respectively, without any C1 products, suggesting a new approach for the design of highly efficient photocatalysts of CO2 for C2 production. Theoretical calculations demonstrate the charge-polarized Zr-O-Mo aided the C?C coupling process with the largely reduced energy barrier.

Mechanistic insight into the formation of acetic acid from the direct conversion of methane and carbon dioxide on zinc-modified H-ZSM-5 zeolite

Methane and carbon dioxide are known greenhouse gases, and the conversion of these two C1-building blocks into useful fuels and chemicals is a subject of great importance. By solid-state NMR spectroscopy, we found that methane and carbon dioxide can be co-converted on a zinc-modified H-ZSM-5 zeolite (denoted as Zn/H-ZSM-5) to form acetic acid at a low temperature range of 523-773 K. Solid-state 13C and 1H MAS NMR investigation indicates that the unique nature of the bifunctional Zn/H-ZSM-5 catalyst is responsible for this highly selective transformation. The zinc sites efficiently activate CH4 to form zinc methyl species (-Zn-CH3), the Zn-C bond of which is further subject to the CO2 insertion to produce surface acetate species (-Zn-OOCCH3). Moreover, the Bronsted acid sites play an important role for the final formation of acetic acid by the proton transfer to the surface acetate species. The results disclosed herein may offer the new possibility for the efficient activation and selective transformation of methane at low temperatures through the co-conversion strategy. Also, the mechanistic understanding of this process will help to the rational design of robust catalytic systems for the practical conversion of greenhouse gases into useful chemicals.