167156-83-4Relevant academic research and scientific papers
Conversion of Chiral Oxiranes into Chiral Aziridines with Retention of Configuration by Way of Chiral Episulfonium Ions and Reactions of the Aziridines with Grignard Reagents
Toshimitsu, Akio,Abe, Hideyuki,Hirosawa, Chitaru,Tamao, Kohei
, p. 3465 - 3472 (2007/10/02)
Chiral oxiranes are converted into chiral aziridines with overall retention of configuration by means of sulfur chemistry.The key step of this procedure is the transformation of the organosulfur intermediates, i.e., the replacement of a hydroxy group boun
Asymmetric Radical Reaction in the Coordination Sphere. 2. Asymmetric Addition of Alkane- and Arenesulfonyl Chlorides to Olefins Catalyzed by a Ruthenium(II)-Phosphine Complex with Chiral Ligands
Kameyama, Masayuki,Kamigata, Nobumasa,Kobayashi, Michio
, p. 3312 - 3316 (2007/10/02)
The addition of arenesulfonyl chlorides to styrene in the presence of a catalytic amount of a ruthenium(II) complex with chiral phosphine ligands, Ru2Cl43 or Ru2Cl43, proceeds under mild conditions to give optically active 1:1 adducts,
