16735-15-2

Basic information

• Product Name: 6-methyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one
• CAS NO: 16735-15-2
• Molecular Weight: 186.254
• Mol File: 16735-15-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 6-methyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6-methyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one(16735-15-2)
• EPA Substance Registry System: 6-methyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one(16735-15-2)

Safety Data

• Hazardous Substances Data: 16735-15-2(Hazardous Substances Data)

Upstream product

• 104-93-8 p-methylanizole 
• 71-43-2 benzene 
• 106-44-5 p-cresol 
• 589-92-4 1-methylcyclohexan-4-one 
• 598-32-3 2-hydroxy-3-butene 
• 93-55-0 1-phenyl-propan-1-one 
• 2100-17-6 4-pentenal 
• 536-74-3 phenylacetylene 
• 15036-22-3 1-phenyl-2-methylcyclohexanol 
• 17429-36-6 4-methyl-4-phenylcyclohex-2-enone 

Downstream Products

• 50715-86-1 4-methyl-3-phenylphenol 
• 92035-61-5 1-Methyl-2-phenyl-cyclohexanol-⁽⁴⁾ 
• 72316-02-0 4-methyl-3-phenyl-cyclohexene 

Relevant articles and documents

Palladium mediated one-pot synthesis of 3-aryl-cyclohexenones and 1,5-diketones from allyl alcohols and aryl ketones

One-pot synthesis of Robinson annulated 3-aryl-cyclohexenones from allyl alcohols and ketones using palladium is reported. Long chain aliphatic or aryl substitutions at the C1 position of allyl alcohol result in the formation of 1,5-diketone products. This simple one-pot method avoids the use of highly electrophilic vinyl ketones.

Copper/Selectfluor-System-Catalyzed Dehydration-Oxidation of Tertiary Cycloalcohols: Access to β-Substituted Cyclohex-2-enones, 4-Arylcoumarins, and Biaryls

A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols. Thus, by using 2 equiv. of Selectfluor at 25 C, the dehydration-oxidation of tertiary cyclohexanols and oxabenzocyclohexanols gave β-substituted cyclohex-2-enones and 4-arylcoumarins, respectively; whereas the dehydration-oxidation of tertiary cyclohexanols gave biaryls as the final products by using 2.5 equiv. of Selectfluor at 80 C. A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols.

Gold(I) catalyzed isomerization of 5-en-2-yn-1-yl acetates: An efficient access to acetoxy bicyclo[3.1.0]hexenes and 2-cycloalken-1-ones

The gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functionalized acetoxy bicyclo[3.1.0]hexenes is described. The mild reaction conditions employed allow the efficient and rapid synthesis of a variety of such bicyclic compounds via a sequence of two gold(I)-catalyzed isomerization steps. Acetoxy bicyclo[3.1.0]hexenes products can be further transformed to 2-cycloalkenones by simple methanolysis. Copyright