16754-50-0

Usage

Uses

Used in Pharmaceutical Industry:
ALLYL ORTHOFORMATE is used as a reagent for the synthesis of various pharmaceuticals, contributing to the development of new medications and therapeutic agents.
Used in Fragrance Industry:
ALLYL ORTHOFORMATE is used as a reagent for the production of fragrances, enhancing the creation of diverse and complex scents for various applications.
Used in Organic Synthesis:
ALLYL ORTHOFORMATE is used as a solvent and intermediate in the synthesis of other organic compounds, facilitating the formation of a wide range of chemical products.
Used in Research and Development:
ALLYL ORTHOFORMATE is used as a component in research and development processes, enabling scientists to explore new chemical reactions and applications.

InChI:InChI=1/C10H16O3/c1-4-7-11-10(12-8-5-2)13-9-6-3/h4-6,10H,1-3,7-9H2

Upstream product

• 67-66-3 chloroform 
• 107-18-6 allyl alcohol 
• 74-90-8 hydrogen cyanide 
• 75-46-7 trifluoromethan 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 108888-50-2 3-(2,2-Bis-allyloxy-ethyl)-5,5-dimethyl-cyclohex-2-enone 
• 73376-04-2 2,3-epoxypropyl formate 
• 556-52-5 oxiranyl-methanol 
• 5365-14-0 2,2-dichlorocyclopropanecarboxylic acid 
• 48149-74-2 allyl D-glucopyranoside 
• 2595-07-5 allyl D-galactopyranoside 
• 182212-07-3 α,β-O-allyl-D-mannopyranoside 
• 56318-28-6 (bis(allyloxy)methyl)benzene 

Relevant academic research and scientific papers

Green preparing orthoformate cleaning process

The invention provides a green process for preparing orthoformate. A hydrogen chloride alcohol solution is prepared from a byproduct hydrogen chloride tail gas of the chlorine-related synthesis industry and then is slowly added into a reaction system, so that loss caused by escape of hydrocyanic acid is reduced, the yield is increased, great equipment corrosion caused by the byproduct hydrochloric acid prepared by the companies is avoided, the economic additional value of the byproduct hydrogen chloride is greatly increased, three wastes are avoided, the byproduct only comprises ammonium chloride, resources are reasonably utilized, and the green process for preparing the orthoformate is an environment-friendly production process and has a good social benefit.

Alcoholysis of fluoroform

Fluoroform (CHF3) reacts with alkali metal alkoxides MOR (M = Na, K) in the corresponding alcohols ROH (R = Me, Et, i-Pr, t-Bu, and Allyl) at 80-120°C to give orthoformate esters HC(OR)3 in 55-90% yield. Particularly notable is the f

A practical synthetic method for α- and β-glycosyloxyacetic acids

Dihydroxylation of allyl 2,3,4-tri-O-benzyl-6-O-tritylglycosides provides diols, the anomers of which can easily be separated by column chromatography in a practical scale. These anomers can be cleanly transformed into α- and β-glycosyloxyacetic acids, respectively, via oxidative cleavage of the diol followed by oxidation.

REACTION OF DICHLOROCARBENE WITH ALLYL AND CINNAMYL ALCOHOLS

In the reaction of dichlorocarbene, generated by the phase-transfer method, with allyl and cinnamyl alcohols both the products from addition of the dichlorocarbene to the double bond and the products from substitution of the hydroxyl group by a chlorine atom and simultaneous addition of dichlorocarbene at the double bond are formed.