Chemistry - A European Journal p. 1757 - 1764 (1997)
Update date:2022-09-26
Topics:
Piquet, Valerie
Baceiredo, Antoine
Gornitzka, Heinz
Dahan, Francoise
Bertrand, Guy
[Bis(dicyclohexylamino)phosphino]trimethylsilylcarbene (1) reacts with benzonitrile leading to the corresponding 2-phosphino-2H-azirine 3 in 85% yield. Treatment of 3 with trifluoromethanesulfonic acid, methyl trifluoromethanesulfonate, or elemental sulfu
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