16806-96-5Relevant articles and documents
Transition-Metal-Free Approach to Polysubstituted Furans
You, Changming,Zhang, Zhenming,Tu, Yongliang,Tang, Hong,Wang, Yuanfeng,Long, Da,Zhao, Junfeng
, p. 3902 - 3910 (2020/03/23)
A convenient and straightforward strategy for the synthesis of 2,3-disubstituted and 2,3,5-trisubstituted furans via a base-promoted domino reaction of β-keto compounds with vinyl dichlorides is described. This transition-metal-free approach proceeds under operationally simple reaction conditions featuring easily available starting materials, a broad substrate scope, and good functional group tolerance.
Diethylene Glycol Serving as Ethyne Equivalent: A Sustainable Approach toward 2,3-Disubstituted Furan
Yu, Jin-Tao,Shi, Bo,Peng, Haibo,Sun, Song,Chu, Haoke,Jiang, Yan,Cheng, Jiang
supporting information, p. 3643 - 3645 (2015/08/18)
In the presence of tert-butyl peroxide (TBHP), the copper-catalyzed annulation of 1,3-dicarbonyl compound with diethylene glycol was developed leading to 2,3-disubstituted furan. Diethylene glycol serves as a cheap and environmentally friendly equivalent of ethyne, with the release of H2O and alcohol as clean wastes. The procedure involves a sequential O- and C- functionalization of β-ketoester by diethylene glycol.
Selenium Heterocycles. XXXIII (1). Synthesis of Thienofuran, Selenofuran, Thienoindole and Selenoindole. Four Heterocycles
Shafiee, A.,Sattari, S.
, p. 227 - 231 (2007/10/02)
Starting from the readily available 2-methyl-3-benzoylfuran, 1-phenylthienofuran and 1-phenylselenofuran were prepared.Also, starting from phenyl 3-methyindol-2-yl ketone and aryl 2-methylindole-3-yl ketones a series of substituted thieno3,