17024-44-1

Basic information

• Product Name: 5-methyl-6-oxabicyclo[3.1.0]hexan-2-one
• CAS NO: 17024-44-1
• Molecular Formula: C₆H₈O₂
• Molecular Weight: 112.1265
• Mol File: 17024-44-1.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 174.9°C at 760 mmHg
• Flash Point: 68.2°C
• Density: 1.249g/cm³
• Vapor Pressure: 1.18mmHg at 25°C
• Refractive Index: 1.523
• CAS DataBase Reference: 5-methyl-6-oxabicyclo[3.1.0]hexan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methyl-6-oxabicyclo[3.1.0]hexan-2-one(17024-44-1)
• EPA Substance Registry System: 5-methyl-6-oxabicyclo[3.1.0]hexan-2-one(17024-44-1)

Safety Data

• Hazardous Substances Data: 17024-44-1(Hazardous Substances Data)

Upstream product

• 2758-18-1 3-Methyl-2-cyclopenten-1-one 
• 7732-18-5 water 
• 56-93-9 benzyltrimethylammonium chloride 
• 5296-50-4 1-methyl-4,4-dichlorocyclopentene 

Downstream Products

• 765-70-8 3-methyl-1,2-cyclopentanedione 
• 5739-17-3 2-methyl-3-pentyl-2-cyclopentenone 
• 50397-92-7 3-methyl-2-phenylcyclopent-2-en-1-one 
• 26029-34-5 2-methyl-3-phenyl-2-cyclopentenone 
• 1121-05-7 2,3-dimethylcyclopent-2-enone 
• 404001-73-6 7-hydroxy-1,7-dimethyl-spiro[2,4]heptan-4-one 
• 404001-73-6 7-hydroxy-1,7-dimethyl-spiro[2,4]heptan-4-one 
• 404001-73-6 7-hydroxy-1,7-dimethyl-spiro[2,4]heptan-4-one 
• 404001-70-3 (1R,2S,5S)-5-Methyl-2-((E)-propenyl)-6-oxa-bicyclo[3.1.0]hexan-2-ol 
• 404001-70-3 (1R,2S,5S)-5-Methyl-2-((Z)-propenyl)-6-oxa-bicyclo[3.1.0]hexan-2-ol 

Relevant articles and documents

Catalytic asymmetric epoxidation of 2-cyclopentenones

The first highly efficient asymmetric epoxidation of 2-cyclopentenones has been developed. Using a newly designed and readily available Cinchona amine catalyst, 2-cyclopentenones are reacted with hydrogen peroxide to give the corresponding epoxycyclopentanones in high yields and excellent enantioselectivities. Copyright

Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones

Efficient, mild and selective epoxidation of α,β-unsaturated aldehydes and ketones was performed using polyvinylpyrrolidonesupported Oxone (Oxone/PVP) and ButOOH/PVP.

Highly efficient epoxidation of α,β-unsaturated ketones by hydrogen peroxide with a base hydrotalcite catalyst prepared from metal oxides

The base hydrotalcite, prepared from MgO and Al2O3, acted as a highly efficient catalyst for the epoxidation of α,β-unsaturated ketones using aqueous hydrogen peroxide as an oxidant. This heterogeneous epoxidation has the advantages of a high efficiency of H2O2 utilization without organic solvents, a simple workup procedure, and reusability of the hydrotalcite catalyst.