170456-60-7

Basic information

• Product Name: S-(2,4-difluorophenyl)dimethylthiocarbamate
• Synonyms: S-(2,4-difluorophenyl)dimethylthiocarbamate
• CAS NO: 170456-60-7
• Molecular Weight: 217.239
• Mol File: 170456-60-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-(2,4-difluorophenyl)dimethylthiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(2,4-difluorophenyl)dimethylthiocarbamate(170456-60-7)
• EPA Substance Registry System: S-(2,4-difluorophenyl)dimethylthiocarbamate(170456-60-7)

Safety Data

• Hazardous Substances Data: 170456-60-7(Hazardous Substances Data)

Upstream product

• 367-27-1 2,4-difluorophenol 
• 170456-59-4 O-(2,4-difluorophenyl)dimethylthiocarbamate 

Downstream Products

• 1996-44-7 2,4-difluorothiophenol 
• 170456-58-3 5--6-(2,4-difluorophenylthio)-1-indanone 
• 158205-22-2 6-<(2,4-difluorophenyl)thio>-5-nitro-1-indanone ethylene ketal 
• 158205-05-1 5-methanesulfonamido-6-(2,4-difluorophenylthio)-1-indanone 
• 158205-23-3 5-amino-6-<(2,4-difluorophenyl)thio>-1-indanone 

Relevant articles and documents

A high temperature investigation using microwave synthesis for electronically and sterically disfavoured substrates of the Newman-Kwart rearrangement

Electronically deactivated and/or sterically hindered substrates undergo the Newman-Kwart rearrangement (NKR) at around 300 °C, beyond the range of most convenient and safe, small-scale laboratory equipment. We report here the convenient conversions of several difficult substrates using modern microwave technology, which has proven ideal for investigating this high temperature reaction in all but the?most refractory of cases. In addition, several previously reported difficult examples were re-investigated, and found not to require high temperatures under these conditions, for various reasons which are elaborated upon.